ISSN:
1573-1111
Keywords:
modified cyclodextrin
;
inclusion complex
;
fluorescence
;
molecular mechanics
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract An appending moiety of modified cyclodextrins acts as an intramolecular guest and forms a self-inclusion complex in aqueous solution. In this study, the stability of self-inclusion complexes of modified cyclodextrins which have a p-dimethylaminobenzene moiety was analyzed by fluorescent decay analyses, and the factor that determines the stability of the self-inclusion complex was determined by a computational approach. The self-inclusion form is stabilized mainly due to van der Waals interaction between the appending moiety and the cyclodextrin ring.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1008031511486
Permalink