ISSN:
1572-901X
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Summary The kinetics and mechanisms of the oxidation of Nb(CN) inf8 sup5− by the oxyanions S2O inf8 sup2− , BrO inf3 sup− , and IO inf4 sup− have been investigated in alkaline aqueous media (pH 12). The second-order rate constant for the electron transfer reaction between Nb(CN) inf8 sup5− and S2O inf8 sup2− at 25.0 °C, I = 0.36m (K+), is 11.1± 0.3 m −1 s −1 with ΔH
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00165967
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