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  • 1
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 2533-2542 
    ISSN: 0887-6266
    Schlagwort(e): organic-inorganic nanocomposites ; sol-gel ; poly(ethyleneoxide) ; EPR ; NMR ; molecular and macromolecular dynamics ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Organic-inorganic nanocomposite gels comprising poly(ethyleneoxide) chains grafted between silica particles have been studied by electron paramagnetic and nuclear magnetic resonances. Motional heterogeneity has been investigated as a function of gelation and drying by paramagnetic probes dissolved in the organic phase or grafted onto the inorganic nodes. The organic phase exhibits marked variations in dynamic behavior with the liquid-like mobility of the polymer chains strongly hindered at the silica nodes. The conclusions of the EPR study are confirmed by liquid- and solid-state carbon-13 NMR measurements. © 1996 John Wiley & Sons, Inc.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 7 (1997), S. 123-133 
    ISSN: 1057-9257
    Schlagwort(e): nanocomposites ; sol-gel ; heteropolymetallates ; photochromics ; holographic data storage ; amplitude grating ; two-wave-mixing recording ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: This paper describes the properties of some new organic-inorganic photochromic layers. They are based on a hybrid organic-inorganic matrix in which tungsten heteropolyoxometallates (SiW12O4-40, PW12O3-40) are entrapped in a network obtained from the reaction of 3-glycidoxy-propyltrimethoxysilane. The high homogeneity of these materials on the nanoscale leads to transparent monoliths and layers of controlled thicknesses up to 40 μm. The optical properties of the blend are emphasised and the construction of amplitude gratings in the materials by two-wave-mixing experiments is described. The results of the optical experiments and the comparison with the theoretical background are used as a model for photochromic holographic storage processes. © 1997 John Wiley & Sons, Ltd.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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