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  • 1995-1999  (5)
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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic properties of giant magnetostrictive Sm–Fe and Sm–Fe–B thin films are systematically investigated over a wide composition range from 14.1 to 71.7 at. % Sm. The amount of B added ranges from 0.3 to 0.8 at. %. The microstructure mainly consists of an amorphous phase in the intermediate Sm content range from 20 to 45 at. %. Together with an amorphous phase, crystalline phases of Fe and Sm also exist at low and high ends of the Sm content, respectively. Well-developed in-plane anisotropy is formed over the whole composition range, except for the low Sm content below 15 at. % and the high Sm content above 55 at. %. As the Sm content increases, the saturation magnetization decreases linearly and the coercive force tends to increase, with the exception of the low Sm content where very large magnitudes of the saturation magnetization and the coercive force are observed due to the existence of the crystalline α-Fe phase. The coercive force is affected rather substantially by the B addition, resulting in lower values of the coercive force in the practically important Sm content range of 30–40 at. %. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The metal oxides MgO, BaO, Al2O3, SiO2, MgO–Al2O3, CaO–Al2O3, SrO–Al2O3, BaO–Al2O3 and MgO–SiO2 have been coated onto ribbons of the Fe-based amorphous alloy Metglas 2605S3A using a sol–gel process. The effects of the surface coating on the magnetic properties of the alloy are investigated. The d.c. hysteresis loop for ribbons coated with MgO and MgO–Al2O3 is more square shaped than that for the uncoated ribbon. For ribbons coated with BaO, SrO–Al2O3 and BaO–Al2O3 it is more inclined than for the uncoated ribbon. Significant differences in the frequency dependence of the effective permeability are observed that depend on the nature of the coated oxides. The core loss is also affected by the coating. These results may be explained in terms of a stress induced by the coating and the modification of the domain structure via elastic and/or magnetoelastic interactions. It is thought from the magnetoelastic interactions that the MgO and MgO–Al2O3 coatings induce tensile stresses whilst those of BaO, SrO–Al2O3 and BaO–Al2O3 induce compressive stresses.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Archive for rational mechanics and analysis 130 (1995), S. 315-342 
    ISSN: 1432-0673
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Temperature-programmed desorption (TPD) and electron spin resonance (ESR) techniques have been employed to investigate the oxygen adsorbed on the paramagnetic defect centers in dehydroxylated AlPO4-20, AlPO4-11, AlPO4-5, and VPI-5 molecular sieves. Two different adsorption sites are observed for the small-pore AlPO4-20, where oxygen is entrapped within the intracrystalline voids generated during the calcination step, as well as within the β-cages. However, the unidimensional molecular sieves AlPO4-11, AlPO4-5, and VPI-5 have only one type of adsorption site within their inner pores. The apparent activation energies of desorption (12.0-21.7 kcal mol-1) determined from the oxygen TPD results demonstrate that, as the pore size of the AlPO4 molecular sieve is larger, the interaction between the adsorbed oxygen and the molecular sieve framework becomes weaker.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Solidification behavior of Al-20 wt% Si-8 wt% Fe and Al-30 wt% Si-5 wt% Fe alloys during cooling with a cooling rate of 10 K/min has been studied using optical microscopy, X-ray diffractometry, differential thermal analysis, scanning electron microscopy and energy dispersive X-ray spectroscopy. In Al-20Si-8Fe alloy, metastable δ-Al4FeSi2 phase with tetragonal structure formed first from melt, followed by primary Si precipitation and then remaining liquid solidified finally into ternary eutectic of α-Al, Si and δ phases. However, in Al-30Si-5Fe alloy, primary Si formed first, followed by the δ phase precipitation and then eutectic solidification. During isothermal heat treatment of as-solidified alloys, phase transformation from the δ phase to equilibrium β phase began at the interface between δ phase and α-Al matrix and progressed toward the inside of δ phase with co-precipitation of Si particles due to the difference in composition between δ-Al4FeSi2 and β-Al5FeSi phases.
    Type of Medium: Electronic Resource
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