ISSN:
1600-5740
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
Pb5Al3F19 at 160 K is ferroelectric, crystallizing in the tetragonal system. With Mr = 1477.9, the space group is I4cm and a = 14.07 (2), c = 7.30 (1) Å, V = 1445 (3) Å3, Z = 4, Dx = 6.793 Mg m−3. For λ(Mo Kα) = 0.71073 Å, μ = 56.36 mm−1. F(000) = 2480 Pb5Al3F19 undergoes a first-order phase transition on cooling at 120 K and on heating at 270 K. The structure was determined from 656 independent F(hkl) with I〉 3σ(I) and refined by least squares to R = 0.0527, wR = 0.0480, S = 1.065. No atom is further than 0.83 Å, from the hypothetical I4/mcm atomic positions, hence the crystal is structurally ferroelectric. The mean atomic polar displacement of the two independent Al atoms from the zero spontaneous-polarization location, allowing for the F atoms, is 0.207 (28) Å, which leads to a predicted Tc = 860 (230) K. Several additional phase transitions are known to form before the hypothetical phase is attained. Each independent Al atom occupies a fluorine octahedron with average Al—F distance either 1.818 (5) or 1.824 (1) Å. One Pb atom is nine coordinated, occupying a distorted tricapped trigonal prism with average Pb—F = 2.66 (22) Å. The other is ten coordinated, forming a distorted bicapped cuboid, with average Pb—F = 2.61 (28) Å. Pyroelectric pulses are readily detectable in crystals cooled below 120 K, or subsequently on heating to 270 K. Similarly, numerous piezoelectric resonances are observed in the same thermal ranges; the compression mode at 1̃197 kHz has been identified by its characteristic admittance circle. The mechanical quality factor Qm for ferroelectric Pb5Al3F19, determined from the admittance-circle-derived equivalent circuit, is 4̃23.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108768195008366
Permalink
