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  • 1
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 48 (1997), S. 329-356 
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The dynamics of proton dissociation from an acidic moiety and its subsequent dispersion in the bulk is regulated by the physical chemical properties of the solvent. The solvent has to provide a potential well to accommodate the discharged proton, screen it from the negative charge of the conjugated base, and provide an efficient mode for the diffusion of the proton to the bulk. On measuring the dynamics of proton dissociation in the time-resolved domain, the kinetic analysis of the reaction can quantitate the properties of the immediate environment. In this review we implement the kinetic analysis for evaluating the properties of small cavities in proteins and the diffusion of protons within narrow channels. On the basis of this analysis,we discuss how the clustering of proton-binding sites on a surface can endow the surface with enhanced capacity to attract protons and to funnel them toward a specific site.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Wetlands ecology and management 6 (1998), S. 143-150 
    ISSN: 1572-9834
    Keywords: Cyperus papyrus ; Iris pseudacorus ; Israel ; Nuphar lutea ; Nymphaea alba ; wetland restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The draining of the Lake Hula and swamps, northern Israel, during the late 1950s resulted in the loss of a very diverse and rare ecosystem. Oxidation of the peat soil resulted in ground surface subsidence, while heavy autumn winds have eroded the dry peat. Moreover, agriculture on the peat soils is restricted, because of a nitrate surplus. Predictions that the sinking would continue and that more areas would go out of agricultural production led authorities to re-flood a portion of the Hula Valley in 1994. The aim of the present study was to monitor the spontaneous establishment of vegetation in the re-flooded area, the Agmon wetlands, and to reestablish some of the major plant species lost from the valley when Lake Hula was drained. Within the first two years, 74 plant species colonized the wetland spontaneously. Five out of 11 species designated for reintroduction were successfully established. Cyperus papyrus and Cynodon dactylon demonstrated sustainable potential for lake-shore stabilization. Cyperus papyrus was reintroduced from seedlings and rapidly became the dominant riparian species, while Cynodon dactylon established spontaneously. Re-introduced Nymphaea alba clones were established only in enclosures protected from grazing by the semi-aquatic mammal Myocastor coypu. Nuphar lutea and Iris pseudacorus showed better resistance to grazing. These results demonstrate a high potential for successful re-establishment of much of the original Hula swamp macrophytic vegetation by either spontaneous colonization by extant species from the surrounding areas or by introduction of locally extinct species. As such, there is a good chance that the associated faunal components of the former Lake Hula and swamps that have returned to the region since the Hula rehabilitation project commenced will continue to flourish.
    Type of Medium: Electronic Resource
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