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Notes: Abstract The quasigeostrophic theory is used to address the role of diabatic forcing in synoptic scale processes over Iberia. A parametrization of diabatic heating is obtained in terms of a thermodynamic variable called the ice-liquid water potential temperature which is conservative under all phase changes of water. A case study objectively selected by means of a rotated principal component analysis over the diabatic field is analyzed to test the proposed parametrization. This study highlights the fact that the magnitudes of diabatic forcing and dynamic forcing are very nearly the same throughout the troposphere. The results also show that the composite diabatic heating is a better representation for both cloudiness and precipitation fields than the dynamic forcing.

Notes: Abstract The heavy rain event of 30 January to 4 February 1993 in the Segura Basin in SE Iberia is investigated. The study emphasizes the atmospheric processes that led to thunderstorm development. The meteorological scenario has been separated into preconvective and convective periods and into large-scale and subsynoptic settings. The warm, moist air now from the Mediterranean Sea, channelled by a high-over-low blocking pattern with a cold front over southeastern Iberia appears to be the main reason that helped trigger a severe weather occurrence. The study of the mesoscale environment parameters showed an enhanced conditional unstability through a deep troposphere layer with a moderate to strong vertical wind shear that promoted conditions to allow organization of long-lived convective structures.

Notes: Abstract. The chronic toxicity of total ammonium and unionized ammonia (NH3) to the native New Zealand freshwater fingernail clam Sphaerium novaezelandiae was assessed in soft water under laboratory conditions. Control survival after 60 days was high (93%) and concentration-response relationships showed the sensitivity of S. novaezelandiae survival was markedly greater to both total and unionized ammonia (6.4× and 4.6×) after 60 days compared with the 30-day exposure at 20°C. Chronic mortality and number moribund (inability to rebury) showed similar sensitivities, but reproduction was a more sensitive endpoint based on a concentration-response analysis. The survival LC50 values for total and unionized ammonia were 3.8 mg (N)/L (pH 7.5) and 0.037 mg (NH3-N)/L, and reproductive values 0.80 mg (N)/L (pH 7.5) and 0.013 mg (NH3-N)/L at 60 days. No observed effect concentration (NOEC) values for both survival and reproduction were 0.97 mg (N)/L and 0.011 mg (NH3-N)/L, and the lowest observed effect concentration (LOEC) values were 5.4 mg (N)/L and 0.046 mg (NH3-N)/L for survival after 60 days, giving a calculated threshold effect concentration (TEC) of 2.3 mg (N)/L and 0.022 mg (NH3-N)/L. Comparison of the S. novaezelandiae chronic ammonia sensitivity data with the US EPA criteria showed the survival and reproduction TEC values for total ammonia were 1.9× higher than the chronic criterion, and the lethality value 1.4× above the unionized ammonia criterion. The findings suggest that use of the US EPA criteria would provide minimal protection for S. novaezelandiae for chronic ammonia exposure, and that development of site-specific criteria, covering a wide range of environmental conditions, may be required to adequately protect all life stages of this species.

Notes: Abstract. Freshwater macroinvertebrate communities were established within 12 artificial streams or “toroidal” mesocosms and exposed to three replicated concentrations of ammonia for 29 days at constant temperature (16°C) and pH (median 8.4). The criterion units (CU = measured [ammonia]/US EPA 1985 chronic criterion value) of total ammonia in the LOW, MED, and HIGH treatments were 2.0, 4.8, and 13 CUs respectively, and 1.9, 5.8, and 12 CUs for the unionized ammonia. Macroinvertebrates were tolerant of the ammonia exposures with no significant (p 〉 0.1) effect on taxa richness; number of taxa in the orders Ephemeroptera, Plecoptera, and Trichoptera (EPT); or the quantitative macroinvertebrate community index (QMCI), a biotic index proposed for assessing effects of organic enrichment in New Zealand streams. Significant differences (p 〈 0.05) occurred for the mean abundance and the numbers of EPT individuals (QEPT), with the HIGH treatment significantly lower (−41%) than the control for both abundance and QEPT. Of the major species, only the mayflies Deleatidium sp. (Ephemeroptera: Leptophlebiidae) and Coloburiscus humeralis (Ephemeroptera: Oligoneuriidae) showed significant reductions in abundance, with only the caddisflies Beraeoptera roria (Trichoptera: Conoesucidae) and Confluens sp. (Trichoptera: Conoesucidae) showing significant increases in abundance. The abundance of juvenile Deleatidium sp. had a negative concentration-response relationship that resulted in an 82% decrease in abundance in the HIGH treatment. Drift of invertebrates showed no response to ammonia treatments. The 29-day EC50 values for Deleatidium sp. for total and unionized ammonia were 2.15 mg (N)/L (pH 8.4) and 0.145 mg (NH3-N)/L. No observed effect concentration (NOEC) values were 0.95 mg (N)/L and 0.066 mg (NH3-N)/L, and the threshold effect concentration (TEC) was 1.49 mg (N)/L and 0.102 mg (NH3-N)/L. Comparison of the Deleatidium sp. chronic ammonia sensitivity data with the US EPA 1985 chronic criterion value (CCC = 0.45 mg [N]/L, pH 8.4, 16°C) showed the TEC value for total ammonia was 3.3× CCC, and 2.2× higher than the updated US EPA 1998 criteria. The findings suggest that use of the US EPA criteria would provide minimal protection for Deleatidium for chronic ammonia exposure, and that development of site-specific criteria, covering a wide range of environmental conditions, may be required to adequately protect this species.

Notes: Abstract Measurements of contact angle for water, glycerol, formamide and diiodomethane on surfaces of zirconia ceramic stabilized with 4% magnesia, zirconia ceramic stabilized with 3% yttria, zirconia ceramic stabilized with 5% yttria, tetragonal-Y-zirconia ceramic, cubic-Y-zirconia ceramic, zirconium (IV) oxide, aluminum oxide, magnesium oxide and yttrium oxide were conducted. Using the values of contact angle, the total surface free energy of these solids, and its components resulting from different kinds of intermolecular interactions were calculated. It was found that the Lifshitz-van der Waals component of the surface free energy of zirconia ceramics only slightly depends on the amount and kind of metal oxides present in the ceramics. The acid-base component of all the studied solids is lower than 13 mJ/m2, showing a small dependence on the kind of metal oxide. For all samples studied the electron-donor parameter of the acid-base components of the surface free energy is many times higher that electron-acceptor one. It was stated that the acid-base component probably depends on the density of OH groups on the surface of the solids studied.