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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 358 (1997), S. 599-603 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The generation of volatile species of silicon as a means to introduce silicon into an inductively coupled plasma has been studied. It is based on the reaction between silicon and fluoride ions in sulfuric acid media and it was carried out using different flow injection mountings. The first mounting works with an injection of 100 μL concentrated sulfuric acid and 150 μL silicon standard solution in a continuous 0.05 mol L–1 NaF solution flow. The method shows a linear response between the intensity of emission at 251.611 nm line and the silicon concentration from 0.1 to 200 μg mL–1, with a reproducibility of 2% and a detection limit of 0.004 μg mL–1. The second mounting produces the volatile species by the reaction between two opposed aerosol flows in a home-made nebulization chamber. This chamber has a Cross-Flow and a Meinhard nebulizer at either end. A linear response ranging from 0.1 to 1000 μg mL–1 of silicon solution is obtained and the reproducibility rises to 8%.The detection limit reached is 0.02 μg mL–1. The silicon content in real water samples was determined by applying both the above-mentioned methods and a third method for reference.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1436-5073
    Keywords: Keywords. Arsenic determination; flame atomic absorption; chloride volatilization; insectide sample.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract.  The generation of volatile species of As(III) as a means to introduce arsenic into a flame atomic absorption spectrometer has been studied. The method is based on the reaction between As(III) and chloride ions in sulphuric acid medium. The reaction is performed in a discontinuous or batch mode. With this method 130 μl of a solution containing 17.5% (w/v) sodium chloride and As(III) are injected by a 500 ml.min−1 N2 carrier gas flow into 1 ml of concentrated sulphuric acid. The gaseous compounds generated are introduced into the spectrometer through the nebulizer and As is determined.
    Type of Medium: Electronic Resource
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