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  • 1995-1999  (2)
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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Quantitative evidence of a ferromagnetic Fe-rich minor phase present in both melt-quenched/die-upset and sintered magnets based on the Nd2Fe14B composition is presented. Full hysteresis loops were obtained at elevated temperatures (650 K≤T≤800 K) and were subsequently decomposed to obtain the saturation magnetization Ms of the minor phase as well as the paramagnetic slope of the 2-14-1 major phase as a function of temperature. Assuming a composition of pure iron, the calculated volume % of the impurity phase in the die-upset magnets is consistent with that obtained from previous observations of the widths and geometry of the intergranular phase found in the same magnets. The magnetization of the ferromagnetic impurity phase in the melt-quenched magnets decreases more rapidly than that of pure iron; extrapolation indicates a Curie temperature in the range 925 K≤T≤975 K. The paramagnetic susceptibility of the Nd2Fe14B main phases exhibits Curie–Weiss behavior with the same paramagnetic Curie temperature for both sintered and die-upset samples. The Curie constants differ, however, probably due to the different degrees of crystallographic alignment. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In connection with a previous work, magnetic and crystallographic properties of the off-stoichiometric compounds R2Fe14Si2 of the R2Fe17-type are studied. Magnetization curves at T=5 K are observed in a high magnetic field up to 15 T for loose powders as well as for field-aligned powders of the samples expressed in the title. Temperature dependencies of the spontaneous magnetizations are also determined in the temperature region from 5 K to the respective Curie temperature. Detailed x-ray analysis is carried out for Y2Fe14Si2. Conclusions are as follows: (1) the Si substitution brings about significant displacements of the 12j-site Fe as well as the dumbell-site Fe from their original positions, which is discussed in connection with other present experimental data such as the remarkable enhancement of the Curie temperature caused by the Si substitution; (2) averaged Fe moment reduction is strictly determined for the present samples; (3) all the samples have a planer anisotropy at room temperature, taking this fact the magnetization curves for the field-aligned samples are analyzed; (4) exchange interaction between R sublattice and Fe sublattice has been determined for all the samples. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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