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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 89 (1996), S. 351-361 
    ISSN: 1573-2932
    Keywords: organohalogen ; AOX ; organochlorine ; pH ; soil ; production ; mineralisation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The total amount of organically bound halogens was determined in soil samples from the Palace Leas meadow hay plots, Northumberland, UK. These plots have been amended with different combinations of farmyard manure, potassium chloride, ammonium sulphate or nitrate since their establishment in 1897, resulting in, among other things, substantial pH differences between the plots. It was found that the amount of organically bound halogens increased significantly with decreasing pH. Net changes in amounts of organohalogens were also studied in soil obtained from a coniferous forest in southern Sweden. The collected soil was divided into four sets of samples, which were incubated in a climate chamber and subjected to different treatment regimes that influence soil pH. Significant changes in amounts of organically bound halogens were detected in three of the four sets of samples, resulting in significantly increasing amounts with decreasing pH. However, although the amount of organically bound halogens detected was related to soil pH in both the field and the experimental study, the net changes observed in the latter investigation were not directly related to soil pH. This shows that net changes in the amount of organically bound halogens in soil are caused by complex processes, and that further studies are needed to clarify the nature of the observed relation between soil pH and amounts of organically bound halogens.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 491-494 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Negative electrospray ionization mass spectrometry (NESI-MS) of a series of native gangliosides containing one, two or three sialic acid groups, sulphatide-I and cholesterol 3-sulphate was undertaken, using a magnetic sector instrument. The results show that NESI-MS of gangliosides leads to the formation of multiple-charged molecular ions of the type [M — H]-, [M — 2H]2- and [M — 3H]3-. The number of charges appears to be correlated to the number of sialic acid groups present. NESI-MS of sulphatide-I predominantly gave ions of type [M — H]- whilst cholesterol 3-sulphate gave a more complex ionization pattern. The sensitivity of the NESI-MS system was enhanced by using water+methanol, 9:1 (v/v) as solvent, containing 300 pmol/μL of NH4HCO3. The application of NESI-MS to these compounds is discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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