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Spectroscopic study of nickel(II) hydroxide surface modifications induced by a small iron(III) addition (1996)

Kamnev, A. A. ; Smekhnov, Alexander A.

Springer

Fresenius' Zeitschrift für analytische Chemie 355 (1996), S. 710-712

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ISSN: 1618-2650

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Comparative Auger electron spectroscopic data on the surface composition and depth profiling for β-Ni(OH)2 and Ni(OH)2 coprecipitated with iron(III) (3 at.%) are given showing a non-uniform distribution of the latter. They are considered together with their structural characteristics obtained using Fourier transform infrared spectroscopy (both samples) and Mössbauer spectroscopy (Fe-containing sample). The results obtained provide an explanation for the specific behaviour of the Fe(III)-doped nickel(II) hydroxide in heterogeneous processes (adsorption, electrocatalysis).

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/s0021663550710

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