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  • 2000-2004  (2)
  • 1990-1994  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 38 (2000), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Nitrate is now recognized as a widespread ground water contaminant, which has led to increased efforts to control and mitigate its impacts. This study reports on the long-term performance of four pilot-scale field trials in which reactive porous barriers were used to provide passive in situ treatment of nitrate in ground water. At two of the sites (Killarney and Borden), the reactive barriers were installed as horizontal layers underneath septic system infiltration beds; at a third site (Long Point), a barrier was installed as a vertical wall intercepting a horizontally migrating septic system plume; and at the fourth site (North Campus), a barrier was installed as a containerized subsurface reactor treating farm field drainage water. The reactive media consisted of 15% to 100% by volume of waste cellulose solids (wood mulch, sawdust, leaf compost), which provided a carbon source for heterotrophic denitrification. The field trials have been in semicontinuous operation for six to seven years at hydraulic loading rates ranging from six to 2000 L/day. Trials have been successful in attenuating influent NO3- (or NO3-+ NH4+ at Borden) concentrations averaging from 4.8 mg/L N at North Campus to 57 mg/L N at Killarney, by amounts averaging 80% at Killarney, 74% at Borden, 91 % at Long Point, and 58% at North Campus. Nitrate consumption rates were temperature dependent and ranged from 0.7 to 32 mg L N/day, but did not deteriorate over the monitoring period. Furthermore, mass-balance calculations indicate that carbon consumption by heterotrophic denitrification has so far used only about 2% to 3% of the initial carbon mass in each case. Results suggest that such barriers should be capable of providing NO3- treatment for at least a decade or longer without carbon replenishment.Reactive barriers have now been used to treat nitrate contamination from a variety of sources including septic systems, agricultural runoff, landfill leachate, and industrial operations. This demonstration of successful long-term operation should allow this technology to become more widely considered for nitrate remediation, particularly at sites where passive treatment requiring a minimum of maintenance is desired.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 41 (2003), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Review of phosphate behavior in four mature septic system plumes on similar textured sand has revealed a strong correlation between carbonate mineral content and phosphate concentrations. A plume on calcareous sand (Cambridge site, 27 wt % CaCO3 equiv.) has proximal zone PO4 concentrations (4.8 mg/L P average) that are about 75% of the septic tank effluent value, whereas three plumes on noncalcareous sand (Muskoka, L. Joseph, and Nobel sites, 〈1 wt % CaCO3 equiv.) have proximal zone phosphate concentrations (〈0.1 mg/L P) that are consistently less than 2% of the effluent values. Phosphate attenuation at the noncalcareous sites appears to be an indirect result of the development of acidic conditions (site average pH 3.5 to 5.9) and elevated Al concentrations (up to 24 mg/L), which subsequently causes the precipitation of Al-P minerals such as variscite (AlPO4. 2H2O). This is supported by scanning electron microscope analyses, which show the widespread occurrence of (Al+P)—rich secondary mineral coatings on sand grains below the infiltration beds. All of these septic systems are more than 10 years old, indicating that these attenuation reactions have substantial longevity.A field lysimeter experiment demonstrated that this reaction sequence can be readily incorporated into engineered waste water treatment systems. We feel this important P removal mechanism has not been adequately recognized, particularly for its potential significance in reducing P loading from septic systems in lakeshore environments.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1435-0157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Detailed monitoring of groundwater in a shallow sand aquifer impacted by a large-flux septic system showed that water quality in the shallow water table zone below the tile bed was similar to that of smaller-flux septic systems in similar hydrologic settings where effluent residency in the unsaturated zone was of similar duration. During residency of about one week in the 4-m thick unsaturated zone, effluent NH+ 4 was largely oxidized to NO− 3, about 75% of DOC was biodegraded, and acidity produced by the above reactions was neutralized by dissolution of calcite. Beneath the tile bed and extending laterally downgradient a distance of 80 m to the Lake Erie shoreline, a distinct plume of impacted groundwater was easily distinguished by elevated levels of electrical conductance, Cl−, NO− 3, HCO− 3, NA+, Ca2+, and K+ and by depressed levels of pH and dissolved oxygen. High NO− 3 levels that occur below the tile bed disappear, however, in the anaerobic plume core zone 10 to 70 m downgradient, apparently as a result of denitrification. The rich reserve of solid-phase organic carbon in the aquifer sediment (2.5%) probably provides much of the organic carbon for heterotrophic denitrification. This condition is in contrast to other septic system plumes in sand aquifers where high NO− 3 levels persist and where aquifer organic carbon values are much lower. Although NO− 3 is attenuated in the plume core, persistence of NO− 3 along the aerobic upper fringe of the plume demonstrates the ability of septic systems to cause significant water-quality degradation of sand aquifers when the conditions favorable for denitrification do not exist. The sharp boundary between the plume water and non-impacted water adjacent to and overlying the plume in the area 50 to 100 m downgradient from the tile bed, and the undiluted nature of non-reactive solutes such as Cl− throughout the core of the plume, demonstrates that dispersion has only a weak influence on the plume. This is consistent with dispersion studies in many other sand aquifers.
    Type of Medium: Electronic Resource
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