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  • 1990-1994  (3)
  • 1980-1984  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 9 (1991), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Metapelites in the Altavista area, southwest Virginia Piedmont, USA, underwent allochemical hydrothermal retrograde metamorphism in synmetamorphic shear zones. The metapelites of the Evington Group were metamorphosed in a prograde sequence of chlorite, staurolite, and sillimanite zones. Garnet–biotite geothermometry and phase relations support eastward increasing metamorphic grade, ranging from 570° C in the staurolite zone to 650° C in the sillimanite zone at c. 5.8 kbar. Sillimanite-zone rocks later underwent progressive retrogression around shear zones which acted as fluid conduits. Retrograde assemblages are successively zoned around the shear zones with staurolite-, chloritoid- and kyanite-bearing assemblages. The shear zones commonly contain kyanite or tourmaline veins. Applicable phase equilibria indicate that retrogression occurred during isobaric cooling through c. 200–270° C. Rock compositional changes with retrogression occurred in steps: SiO2 was gained in the early stages of the retrogression but lost in the late stages; Al2O3, K2O, and H2O were increasingly gained through the sequence; CaO was increasingly lost. Addition of H2O and decreasing temperatures resulted in new ferromagnesian minerals (staurolite, chloritoid, chlorite) and changes in H2O, SiO2, Al2O3, K2O, and CaO contents produced muscovite and sodic plagioclase.Subsequent to prograde metamorphism, deeply derived fluids migrated upwards along shear zones, providing fluid and energy for the retrograde reactions. The sheared rocks underwent fluid infiltration with fluid fluxes of 1.8 × 107–4.3 × 107 cm3/cm2 corresponding to minimum estimated fluid-to-rock ratios of 7.5–21 as a function of position within the shear zone. Fluid flow was from high to low temperature early and low to high temperature later in the retrogression.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 87 (1984), S. 297-309 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the contact aureole of the Lilesville granite and comagmatic Pee Dee gabbro, N.C., greenschist-facies phyllites of the Carolina slate belt have been overprinted by a series of metamorphic reactions producing opx-bearing hornfelses and migmatitic gneisses. In the exterior aureole the slate belt assemblage (chl+ms+ep+ab+qz) gives way to the continuous reaction assemblages (chl+bt+cd+ ms+ab±ep+qz), (bt+cd+ms+An8–29+qz), (bt+cd+ kf+ms+pl+qz), (bt+cd+als±ms+kf+pl+qz), and (bt+cd+ga+kf+pl+qz), from lowest to highest grade. The interior aureole, interpreted as part of the floor of the granite, bears the continuous and discontinuous reaction assemblages (bt+cd+als+kf+pl+qz),(bt+cd+kf+ pl+qz), and, near the gabbro, (bt+cd+ga+opx+kf+ pl+qz). The leucosomes of the migmatitic interior aureole are predominantly trondhjemites with the assemblage (An35–45+qz±bt±cd±kf). Restites in the migmatitic interior aureole contain the AFM assemblages (bt), (bt + cd), (bt+cd+als), and (bt+cd+ga), plus kf, An40–50, and qz. Contact metamorphism was isobaric at 4.0–5.1 or 2.0–3.5 kb depending on choice of aluminosilicate triple point; temperatures reached 650° C in the migmatitic interior aureole and approached 750° C near the gabbro; $${\text{P}}_{{\text{H}}_{\text{2}} {\text{O}}}$$ was less than 0.8 in the migmatites, and was lower in the interior aureole and in the high grade exterior aureole. Partial melting in the migmatitic interior aureole took place during dynamothermal metamorphism caused by the magmatic diapir. Incipient melting occurred by the reaction bt+cd+kf+pl+qz+w = liquid. The melt was H2O-undersaturated and coefficients of the reactants were weighted heavily toward the felsic minerals; the proportion of felsic minerals in the leucosomes was controlled in part by modal abundance of kf, pl, and qz available for melting. The incorporation of K into biotite by subsolidus reactions, coupled with the high thermal stability and low solubility of biotite in a felsic melt, are responsible for the trondhjemitic composition of the early anatectic liquids.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Keywords: 24.10-i ; 25.70.Cd
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Proton and neutron transfer populating low-lying states have been studied in the system144Sm+88Sr at an energy below the Coulomb barrier. The experimental cross sections for the single proton transfer are well reproduced by DWBA-calculations using spectroscopic information from light ion reactions. The two-proton transfer appears enhanced relative to the uncorrelated sequential transfer of single protons. The same holds for the transfer of proton pairs, the enhancement is kept for the second pair. This is interpreted as a supercurrent between two superfluid nuclear proton-pair wave functions: more mass and charge is transported per time unit in pairs than by single nucleons. Neutron transfer is observed with large cross sections and is found to contribute to the energy loss observed in the transfer reactions. For mixed proton-neutron transfers the sequential nature of the transfer reactions is established in a similar way as for the two-proton and two-neutron transfer; in the latter case no enhancement is observed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 541-549 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Automotive paints with clear-coat surfaces can be physically damaged by exposure to acidic reagents produced in a smog chamber designed to reproduce real environmental conditions. Visual and reflectance microscopy observations show that deposition of material formed from the reaction of the clear coat and the reagent drop occurs on the paint surface after the drop evaporates to a critical size, with the greatest deposition occurring at the edge of the drop. This type of deposition suggests a free-energy minimization process favoring the formation of stable nuclei at the reagent drop edge. With heating after the drop evaporation to simulate exposure to the sun, a damaged area containing sulfur that is in the shape of a circular ring is observed at the location of the deposits. The majority of the visual damage appears to result from an interaction between the deposit and the paint at elevated temperatures. Results from profilometry, scanning electron microscopy, and reflectance microscopy show that the damaged areas are ring-shaped cracked blisters on the surface resulting from the clear coat separating into layers. © 1993 John Wiley & Sons, Inc.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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