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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 204-206 
    ISSN: 0749-1581
    Keywords: 2D EXSY NMR ; Complete line-shape analysis ; Aroylcyanoketene-S,S-dimethylacetals ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The applicability of 2D EXSY NMR spectroscopy for studying quantitatively the dynamic behaviour in three aroylcyanoketene-S, S-dimethylacetals was tested by means of 1H NMR spectroscopy. It can be concluded that the method is a reasonable qualitative supplement to complete line-shape analysis.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 212-222 
    ISSN: 0749-1581
    Keywords: Dynamic NMR ; 13C NMR ; Push-pull alkenes ; Restricted C,C and C,N rotation ; π-Electron density distribution ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Push-pull alkenes with variable structure were investigated with respect to the influence of the different substituents at the central C,C double bond on the dynamic behaviour of this type of compound. 1H and 13C NMR spectroscopic investigations were carried out for ketene-S,S-, -S,N- and -N,N-acetals. HMO calculations were employed to discuss the related π-electron density distributions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Advances in Polymer Technology 10 (1990), S. 135-141 
    ISSN: 0730-6679
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Properties of short and especially long fiber reinforced thermoplastics highly depend on fiber length distribution in the processed material and local fiber orientation in the processed part. Good mechanical performance is achieved, if overall mean fiber length is high and fiber orientation is well adapted to the external stress situation. If non optimized processing parameters are applied, a decay in mean fiber length and unfavorably orientated fibers in areas of high stress may result. Knowledge of morphological parameters provides quantitative information about the injection molding process and the design of the cavity. Recent advances in automated methods of measuring fiber length and spatial fiber orientation, which are based on image processing systems, reveal even small differences in morphology. Measuring spatial fiber orientation on polished cross-sections by means of an image processor is a newer concept, that allows fast and quantitative description and optimization of the mold filling process. Some examples show the performance of the method; the measured fiber orientation is used to model thermal expansion and Young's modulus.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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