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  • 1990-1994  (2)
  • thermodynamic properties  (2)
  • 1
    ISSN: 1572-9567
    Keywords: air ; density ; equation of state ; fundamental equation ; heat capacity ; thermodynamic properties ; velocity of sound
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A revised interim formulation for the thermodynamic properties of air has been developed for calculating properties of the vapor and estimating properties for the liquid at temperatures as low as 60 K. The formulation incorporates separate equations for the calculation of bubble-point and dew-point pressures and densities and for the ideal-gas heat capacity. A new fundamental equation of state is given for vapor and liquid states of air based upon available experimental data and predicted values of isochoric heat capacity for the liquid using corresponding states methods. Procedures for predicting C v are discussed. The fundamental equation for air is explicit in nondimensional Helmholtz energy. The terms of the fundamental equation were selected from a larger set of 75 proposed terms using a least-squares fitting procedure. Representative graphical comparisons of calculated property values to experimental measurements are given. The estimated accuracy of calculated densities is generally ± 0.2% except near the dew and bubble lines. Calculated heat capacities for the liquid must be considered only as estimates until substantiated by experimental measurements.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 1572-9567
    Keywords: air ; bubble point ; dew point ; phase equilibrium ; thermodynamic properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract As a companion to a new correlation for the thermodynamic properties of air in single-phase states, new values for the properties on the dew and bubble lines have been calculated. Phase equilibrium properties for air at low and moderate pressures were predicted from accurate equations of state for argon, nitrogen, and oxygen using extended corresponding-states (ECS) methods. For pressures near the critical pressure, property values were calculated using a modified Leung-Griffiths model for mixtures of argon, nitrogen, and oxygen. Available experimental data and newly predicted values have been used in developing new correlating functions for estimating density and pressure on the dew and bubble lines of air. Estimates of the accuracies of these correlations based upon comparisons of calculated properties to data from other sources are also included.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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