ISSN:
1077-3118
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Silicate glasses, Al2O3⋅9SiO2, were successfully prepared to incorporate Sm2+ ions using a sol-gel process. The glasses synthesized through hydrolysis of Si(OC2H5)4, Al(OC4H9)3, and SmCl3⋅6H2O were heated in air, followed by heating in the presence of hydrogen, in which samarium ions were reduced from the trivalent to divalent state. Glasses incorporated with Sm2+ were colorless, transparent, and showed an intense emission with peaks at 683, 700, and 725 nm due to 5D0→7F0,1,2 transitions, respectively, of the Sm2+ ions. Irradiating the glasses with an Ar laser lowered the intensities of emission from Sm2+ ions and did not promote the formation of Sm3+ ions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.112078
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