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  • 1990-1994  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Space science reviews 60 (1992), S. 457-502 
    ISSN: 1572-9672
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The Galileo Near-Infrared Mapping Spectrometer (NIMS) is a combination of imaging and spectroscopic methods. Simultaneous use of these two methods yields a powerful combination, far greater than when used individually. For geological studies of surfaces, it can be used to map morphological features, while simultaneously determining their composition and mineralogy, providing data to investigate the evolution of surface geology. For atmospheres, many of the most interesting phenomena are transitory, with unpredictable locations. With concurrent mapping and spectroscopy, such features can be found and spectroscopically analyzed. In addition, the spatial/compositional aspects of known features can be fully investigated. The NIMS experiment will investigate Jupiter and the Galilean satellites during the two year orbital operation period, commencing December 1995. Prior to that, Galileo will have flown past Venus, the Earth/Moon system (twice), and two asteroids; obtaining scientific measurements for all of these objects. The NIMS instrument covers the spectral range 0.7 to 5.2 μ, which includes the reflected-sunlight and thermal-radiation regimes for many solar system objects. This spectral region contains diagnostic spectral signatures, arising from molecular vibrational transitions (and some electronic transitions) of both solid and gaseous species. Imaging is performed by a combination of one-dimensional instrument spatial scanning, coupled with orthogonal spacecraft scan-platform motion, yielding two-dimensional images for each of the NIMS wavelengths. The instrument consists of a telescope, with one dimension of spatial scanning, and a diffraction grating spectrometer. Both are passively cooled to low temperatures in order to reduce background photon shot noise. The detectors consist of an array of indium antimonide and silicon photovoltaic diodes, contained within a focal-plane-assembly, and cooled to cryogenic temperatures using a radiative cooler. Spectral and spatial scanning is accomplished by electro-mechanical devices, with motions executed using commandable instrument modes. Particular attention was given to the thermal and contamination aspects of the Galileo spacecraft, both of which could profoundly affect NIMS performance. Various protective measures have been implemented, including shades to protect against thruster firings as well as thermal radiation from the spacecraft.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 5 (1991), S. 441-445 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A new ion desorption method is described that utilizes a primary beam of massive, multiply charged cluster ions to generate secondary ions of peptides in a glycerol matrix. The massive cluster ion beam is generated via electrohydrodynamic emission using a 1.5 M solution of ammonium acetate in 30% aqueous glycerol. Negaitve ion spectra of peptides obtained using this technique show greatly decreased relative intensities for fragment ions and ‘chemical noise’ background when compared to spectra obtained using a xenon atom primary beam. The near absence of fragmets derived from radiation damage to the sample solution is attributed to the impact of primary particles with energies less than 1 eV/nucleon.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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