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  • 1990-1994  (2)
Material
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1007-1017 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed that predicts three-dimensional, two-phaseflow, heat transfer and reaction inside catalytic cracking riser-type reactors. The model consists of the full set of partial-differential equations that describe the conservation of mass, momentum, energy and chemical species for both phases in the reactor, coupled with empirical correlations concerning interphase friction, interphase heat-transfer and fluid-to-wall frictional forces. The cracking reaction is simulated by a simple three-lump kinetic model, but more realistic kinetic models can be easily included. The model can predict the most important engineering aspects of a riser reactor including pressure drop, catalyst holdup, interphase slip velocity, catalyst acceleration zone, choking behavior and temperature distribution in both phases, and yields distribution all over the reactor. It can also predict other complex engineering three-dimensional, two-phase problems realistically using computational fluid dynamics techniques.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1799-1809 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nonisothermal adsorption is studied by incorporating its mathematical description into a model consisting of the full two-dimensional Navier-Stokes equations and energy and species concentration equations to simulate the processes in fixed-bed industrial adsorbers/regenerators. The model partial-differential equations are solved numerically by using well-established computational fluid dynamics techniques. The equilibrium between gas and solid is considered nonlinear, which is described by Freundlich-type equations. The transport and adsorption of a compound from a solvent to and into an adsorbent are described by a two-step process: transport through the “film” to the outer surface of the particle and diffusion into the porous particle. The effect of fill resistance is discussed, as well as a two-equation turbulence model. Solutions obtained for a typical industrial adsorber/regenerator demonstrate the potential of this method. The computed results for various flow ratios and parameters in the Freundlich equations are shown to be physically plausible.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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