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  • 1990-1994  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 21-29 
    ISSN: 0392-6737
    Keywords: Infrared and Raman spectra and scattering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary Group-theoretical study of the vibrational modes of chlorosodalite [Na4Al3(SiO4)3]2 has been carried out for theT d 1 space group. The Raman-active modes are evaluated and comparison is made with the experimental results on sodalite. It is shown that the experimental Raman spectrum does not support the structure of sodalite to beT d 1 but confirms it to beT d 1 . Raman scattering studies were performed on X-ray irradiated As-grown single crystal of chloro-sodalite to identify the coloration mechanism. Enhancement of oxygen twisting and stretching mode intensities on X-ray irradiation indicates the formation of neutral sodium colloidal aggregate during the coloration process.
    Type of Medium: Electronic Resource
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