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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Both ac and dc conduction processes through thin Langmuir–Blodgett (LB) films of the dodecyloxyphenylurethane of 2-bromo-5 (2'-hydroxyethoxy) tetracyanoquinodimethan (DDOP-C-TCNQ, a redox-active molecule) sandwiched between dissimilar metal (Pt and Mg) electrodes have been studied. The dc conduction changed from a linear I/V characteristic for the lowest applied voltages (±20 mV) to a symmetric nonlinear characteristic obeying a ln I∝V1/4 dependence for voltages up to ±1.5 V, in as-prepared samples. For larger positive voltages, a large increase in current was observed with the dependence changing to a ln I∝V3 law, a dependence not reported previously for metal/LB film/metal systems. For increased negative voltages, the ln I∝V1/4 was again observed. For low applied ac fields, the conductance was found to follow a ωn law with a value of n close to 0.8. The effect of heat annealing the samples was also studied with significant differences in the observed changes in conductance between bilayer and monolayer structures. Emphasis was placed on understanding the conduction process through the single DDOP-C-BHTCNQ layer film. For the monolayer device, hysteresis is observed in the positive bias, and both as-prepared and annealed samples exhibit ln I∝V3 behavior. Such behavior was not observed for the corresponding negative voltages, indicating rectification across a distance approximated by the length of an individual molecule. Possible models of the three-dimensional arrays for both monolayer and multilayer metal/LB film/Mg structures are presented. The weight of existing experimental results does not support the Aviram–Ratner "molecular rectifier'' concept for presently known Pt/LB monolayer/Mg devices.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 1916-1918 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Metal/Langmuir–Blodgett monolayer/metal devices, where the monolayer consists of the dodecyloxyphenylcarbamate of 2-bromo, 5(2'-hydroxyethoxy) tetracyanoquinodimethan, a donor-σ-acceptor molecular system, have been constructed, and dc current-voltage (I-V) characteristics of these devices were recorded at room temperature. For biases of ±20 mV, the I-V characteristics are linear, changing to a nonlinear form for higher voltages. This nonlinear characteristic exhibited a ln(I)∝V1/4 dependence for both positive and negative voltages up to ±1 V. For positive voltages 〉+2.0 V for as-prepared devices and 〉+1.5 V for annealed devices, a ln(I)∝V3 dependence was observed, revealing a very large increase in current for small voltage changes. Such behavior was not observed for corresponding negative voltages, indicating rectification across a distance approximated by the length of an individual molecule.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 4627-4634 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 113 (1991), S. 2785-2786 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Two experiments were conducted to examine the relationship between sward surface height, herbage intake and liveweight gain in beef cattle grazed on pasture. In Experiment 1, two ‘animal types’ (18 Charolais × Angus steers and 18 Friesian bulls) were continuously grazed for 22 days during the late autumn on replicated swards maintained at sward surface heights of 6, 10 and 15 cm. Herbage intakes, assessed from the faecal concentration of chromium delivered from an intraruminal controlled release capsule and the in vitro digestibility of hand-plucked herbage samples, were curvilinearly related to sward height (r = 0·76, p〈0·0·01). Average liveweight gains were 0·02, 0·61 and 1·31 kg d-1 (P 〈0·05) and increased linearly (r= 0·84, P 〈0·001) with sward height. The maintenance organic matter intakes of the steers and bulls, with initial mean (± s.e.) live weights of 225 ± 15 kg and 172 ± 15 kg respectively, were estimated to be 3·6 and 3·5 kg d-1 respectively. In Experiment 2 (spring) 36 cattle, including 35 of those used in Experiment 1, were reallocated to sward heights of 5, 10 and 15 cm using the same design as for Experiment 1. Average liveweight gains were 0·94, 1·57 and 1·68kg d-1 (p 0·05) and were curvilinearly related to sward height (r= 0·093, p 〈0·05). Maintenance intakes could not be reliably extimated for the cattle in Experiment 2 because few animals had liveweight gains close to zero. These trials confirm that liveweight gain in continuously grazed finishing steers and bulls increases with sward surface height to maximum of 8–10cm with spring ryegrass/white clover pastures while, in autumn, swards of 12–15cm height are required to achieve maximum performance.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Applied microbiology and biotechnology 33 (1990), S. 716-720 
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary The influence of pH, temperature and catechol concentration on germanium (Ge) accumulation byPseudomonas stutzeri AG259 was investigated. Increasing the incubation temperature or pH of the culture medium markedly enhanced Ge accumulation. High amounts of Ge were accumulated at pH 11 and at 50°C, conditions under whichP. stutzeri cells were non-viable. Ge accumulation was unaffected by treatment with toluene or 2,4-dinitrophenol. These results indicate that Ge was accumulated by an energy-independent process. Ge accumulation increased as the catechol concentration increased. The use of autoclaved catechol solutions consistently increased the amount of Ge accumulated at all concentrations of catechol tested. It is possible that Ge enters the bacterial cells as a Ge-catechol complex and this uptake is enhanced by autoclaved catechol.
    Type of Medium: Electronic Resource
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  • 7
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    London : Periodicals Archive Online (PAO)
    Journal of historical geography. 18:3 (1992:July) 339 
    ISSN: 0305-7488
    Topics: Geography
    Description / Table of Contents: Europe
    Notes: Reviews
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Geo-marine letters 11 (1991), S. 132-137 
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Consideration of factors influencing the interaction between a corer and sediment suggest the likelihood of significant and anisotropic straining of the particle framework during coring. Direct observations allow the coring process to be discretised, the relative motion of corer, core and sediment to be visualized and confirm that the development of differences between corer penetration and core length is not a continuous process. Records suggest the possibility of dislocation of the relative positions of porewater and particle framework, which may lead to the disequilibration of sorbed species.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 12 (1990), S. 101-107 
    ISSN: 1573-0581
    Keywords: gravity coring ; core-shortening ; corer penetration ; sample entry ; observations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Gravity core samples provide the basic data source for a wide range of geological, geotechnical and geochemical studies. However, the length of the core recovered is often less than the penetration achieved by the corer, such cores being described as “shortened”. If the penetration of the corer has been measured, and it is assumed that no dropout of the core occurs as the barrel is withdrawn from the seabed, it is present practice to reconstruct in situ dimensions using an overall correction factor based on this penetration and the length of core recovered. However, measurements, reported here, have been made of corer penetration and sample entry and these show that the entry deficit (penetration minus sample entry) develops in some instances continuously, and in others intermittently. These results indicate that an overall correction factor is unlikely to be appropriate to any given section of the core.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic ecology 28 (1994), S. 347-352 
    ISSN: 1573-5125
    Keywords: estuary ; sediment resuspension ; hyperconcentrated benthic layers ; oxygen demand ; modulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Hyperconcentrated benthic layers, which form during neap tides, recruit much of the fine sediment population of the turbidity maximum of a hypertidal estuary. Measurements of tidal amplitude and suspended solids concentration reveal that resuspension of the hyperconcentrated layers occurs between three and eight tides after neap tides rather than during spring tides (12 to 15 tides after neaps). During these resuspension events, dissolved oxygen levels are reduced but recover by spring tides. Peak solids concentrations and critically depressed dissolved oxygen levels are out of phase with tidal current amplitude. Thus observations close to neap and spring tides do not necessaraly capture the extremes of the envelope of water quality conditions.
    Type of Medium: Electronic Resource
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