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  • 1990-1994  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 45 (1994), S. 562-569 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Einfluß der Wärmebehandlung von Cu-Ni 70/30 Legierungen auf die Lochkorrosionsempfindlichkeit in Meerwasser bei verschiedenen TemperaturenMit Proben unterschiedlichen Gefüges aus kommerziellen CuNi 70/30 Legierungen wurden verschiedene Versuchsserien durchgeführt. Das Gefüge der homogenisierten Proben wurde durch Glühbehandlungen modifiziert, wodurch die Korngröße erheblich zunahm und intermetallische Verbindungen ausgeschieden wurden.Elektrochemische Untersuchungen und Versuche bei freier Korrosion erfolgten bei 20, 40, 60 und 80°C in ruhendem Meerwasser mit einem pH-Wert von 8,2 und einem gelösten Sauerstoffgehalt zwischen 6,5 ppm (bei 20°C) und 3,0 ppm (bei 80°C). Die an der Metalloberfläche anhaftenden Korrosionsprodukte wurden mit chemischen und XPS Methoden analysiert.Folgende Befunde konnten festgestellt werden:-bei den homogenisierten und geglühten Proben wurde mit steigender Temperatur eine Abnahme der Korrosionsgeschwindigkeit und der selektiven Kupferauflösung beobachtet.-die geglühten Proben weisen im gesamten Temperaturbereich die höchsten Korrosionsgeschwindigkeiten auf und erleiden Lochkorrosion bei niedriger Temperatur.
    Notes: A series of experiments was carried out on Cu-Ni 70/30 commercial alloy specimens presenting different microstructures. The microstructure of homogeneized specimens was modified with annealing treatments by which grain size significantly increased and intermetallic compounds precipitated, thus creating some dishomogeneity in the alloy.Free corrosion and electrochemical tests were carried out at 20, 40, 60, 80°C in quiescent sea water at pH 8.2 with dissolved oxygen (D.O) content ranging from 6.5 ppm (at 20°C) to 3.0 ppm (at 80°C). The corrosion products adherent to the metallic surface were analyzed with chemical and XPS methods.The following could be observed:-with increasing temperature, a decrease in corrosion rate and selective copper dissolution was observed in homogeneized and annealed specimens-the annealed specimens have the highest corrosion rate in the whole temperature range and undergo pitting corrosion at low temperature.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 21 (1994), S. 442-446 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The corrosion mechanism of Cu-Ni 70/30 alloy in quiescent seawater at 80°C with a dissolved oxygen content of .3.0 ppm was studied with electrochemical and free corrosion tests. The passive films formed on free corroded specimens after an exposure time of 10 min-360 h were analysed with XPS.Free corrosion tests show that Cu-Ni alloy undegoes copper-selective dissolution; the kinetics of the dissolution process are governed by a transport-limited mechanism. Electrochemical tests show that the overall corrosion process is under cathodic control and that the reduction of dissolved oxygen is the most important parameter of the corrosion process. X-ray photoelectron spectroscopy shows that the composition of the passive films changes by changing the exposure time. The main components of the passive films formed on metallic surfaces are Ni compounds after the shorter exposure time and Cu compounds after a longer exposure time.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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