ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The room-temperature polarized Raman scattering of single-crystal Ba [Fe(CN)5NO] · 3H2O, space group Pbcm (D112h, No. 57), in the 2200-10 cm-1 spectral range, and a factor group analysis of the nitroprusside anion vibrational modes are presented. The near parallelism between the anion NCFeNO axis and a crystallographic axis facilitates the interpretation of the spectra. The data obtained complement already existing IR studies and the two series of results together provide reference information for the understanding of the vibrational behaviour of the recently reported electronically excited metastable states of the anion. The Raman data confirm the existence of a relatively large correlation (Davydov) splitting between NO stretching modes due to vibrational coupling between neighbouring nitrosyl groups in the lattice.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250230302
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