ISSN:
0018-019X
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Methyl 2-allyl-3-oxo-2,3-dihydrothiophene-2-carboxylate (2) photocyclizes selectively to methyl 2-oxo-7-thiatricyclo[3.2.1.03,6]octane-1-carboxylate (4). In contrast, 4-thia-2-cyclohexenone 3, on irradiation, affords only low yields of dimers, cycloadducts (2-methylpropene) or RH reduction products (i-ProH).
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/hlca.19850680506
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