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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 93 (1989), S. 6346-6350 
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Journal of medicinal chemistry 30 (1987), S. 1359-1365 
    ISSN: 1520-4804
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 795-806 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: We have studied the photoelectron spectra of BH−3 and BD−3 and have measured the electron affinities of borane; we find EA(BH3)=0.038±0.015 eV and EA(BD3)=0.027±0.014 eV. The peak splittings and intensities demonstrate that the BH−3 ion and the BH3 neutral have very similar geometries; our spectra are consistent with a planar structure for both species. Variational calculations of a coupled oscillator basis over an ab initio potential give an excellent fit to the experimental frequencies and photodetachment Franck–Condon factors. This ab initio model leads to equilibrium geometries with both BH3 and BH−3 as planar molecules with re(BH−3) =1.207 A(ring) and re(BH3)=1.188 A(ring). We find ΔH(open circle)f0(BH−3) =23.1±3.8 kcal mol−1.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 2762-2763 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The 363.8 nm (3.408 eV) photoelectron spectrum of the NH2 (X˜ 2B1)+e−←NH−2(X˜ 1A1) transition of the amide anion is reported. The electron affinity of amidogen is found to be EA(NH2) =0.771 ±0.005 eV. P, Q, and R rotational branches are observed in the spectrum; a simple model which accounts for the band structure is presented.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Capacitance-voltage data are utilized to obtain the free-carrier concentration in n- and p-type Hg1−yCdyTe layers, and to measure the valence-band discontinuity energy of a p-type Hg0.7Cd0.3Te/Cd(4% Zn)Te isotype heterojunction. To facilitate measurement, rectifying contact was made to the Hg1−yCdyTe layers using one of two organic materials—metal-free phthalocyanine and copper phthalocyanine. Contrary to previous results with this heterojunction system, we find that holes are accumulated near the Cd(4% Zn)Te side (rather than Hg1−yCdyTe side). We obtain a valence band discontinuity energy (ΔEv ) equal to (110±20) meV, and a fixed interface charge density of σ=−(5.9±0.3)×1010 cm−2.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 1217-1219 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report the successful growth of ZnTe on nearly lattice-matched III-V buffer layers of InAs (0.75%), GaSb (0.15%), and on GaAs and ZnTe by molecular beam epitaxy. In situ reflection high-energy electron diffraction measurements showed the characteristic streak patterns indicative of two-dimensional growth. Photoluminescence measurements on these films show strong and sharp features near the band edge with no detectable luminescence at longer wavelengths. The integrated photoluminescence intensity from the ZnTe layers increased with better lattice match to the buffer layer. The ZnTe epilayers grown on high-purity ZnTe substrates exhibited stronger luminescence than the substrates. We observe narrow luminescence linewidths (full width at half maximum ≈1–2 A(ring)) indicative of uniform high quality growth. Secondary-ion mass spectroscopy and electron microprobe measurements, however, reveal substantial outdiffusion of Ga and In for growths on the III-V buffer layers.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 65-67 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The viability of ammonia as a sensitizer for the growth of epitaxial Ge on GaAs (100) by laser photochemical vapor deposition (LPVD) has been investigated. Specifically, NH3/GeH4/He (0.8/55.0/95 sccm, 5.5 Torr total pressure) mixtures have been irradiated by an excimer laser beam (ArF, 193 nm) in parallel geometry and for substrate temperatures (Ts) in the range 25≤Ts〈400 °C. As evidenced by a more than an order of magnitude acceleration in the Ge film growth rate (factor of ∼33 improvement at 305 °C), even trace amounts of NH3 added to the gas stream efficiently couple the laser radiation to the Ge precursor (GeH4) without incorporating significant concentrations of N and H into the film. Auger, secondary-ion mass spectrometry (SIMS), and x-ray photoelectron spectroscopy analyses of the films show the nitrogen content to be negligible (〈1%). Also, the slight amount of hydrogen detected by SIMS appears to arise from hydrocarbon contaminants rather than from the ammonia. Transmission electron microscopy studies demonstrate that films grown at Ts≥300 °C are epitaxial with an amorphous overlayer. Embedded within the amorphous matrix are Ge microcrystals which are textured, having their 〈112〉 axes parallel to the substrate normal. The beneficial effect of NH3 on the growth rate of LPVD Ge films is attributed to the photolytic production of hydrogen atoms which efficiently decompose GeH4 by hydrogen abstraction collisions.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 2377-2385 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Measurements of minority-carrier lifetime have been carried out on slices of n-type CdxHg1−xTe (0.2〈x〈0.3) prepared by both normal Bridgman and accelerated crucible rotation (ACRT) Bridgman techniques. Some of these crystals were deliberately doped with a high level of a single impurity. A study of aging effects has been concluded. Lifetime variations with temperature are explained using a combination of band-to-band and Shockley–Read recombination processes. Frequently, a single level 10–30 meV below the conduction-band edge was assumed, but for ACRT crystals it was necessary to postulate a second level. Attempts to identify the origin of the centers, by measurements on doped crystals, were only successful in the case of iron since it acts as a recombination center without providing conduction electrons in CdxHg1−xTe.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 2208-2211 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electron traps in bulk n-type Hg0.7Cd0.3Te were investigated near the HgCdTe/SiO2 interface by use of deep level transient spectroscopy on metal-insulator-semiconductor structures [D. V. Lang, J. Appl. Phys. 45, 3022 (1974)]. Three electron traps are found with activation energies (relative to the conduction band edge) of 0.12, 0.172, and 0.079 eV, and corresponding capture cross sections of 3.5×10−18, 1.1×10−16, and 1.2×10−18 cm2. Depth profiles from the surface to ∼1.0 μm show the concentration of the 0.172-eV trap to be uniform while the 0.12-eV trap shows a strong depth dependence. It is undetectable at the surface, rising in concentration to twice its bulk value at ∼0.5 μm depth then falling to a value comparable with that of the 0.172-eV trap in the bulk (1 μm). Divalent trapping behavior has also been detected. In this case, the deeper state significantly depopulates, enabling a shallower state to then depopulate [J. S. Blakemore, Semiconductor Statistics (Pergamon, London, 1962), p. 156].
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 3699-3710 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The results of photoluminescence analysis of ion-implanted and flash-annealed CdTe are reported here. Bound exciton lines in the spectrum of the CdTe were used to study the annealing of implantation-induced damage in the crystal. The intensity and width of these lines are a very good indicator of variations in lattice strain. Optimum flash annealing conditions were found to depend on both the energy and the dose of the implant. The photoluminescence indicates that flash annealing can provide complete annealing of the crystal damage following implantation. Implanting Cu or B ions into the lattice did not, however, lead to significant variations in the spectrum of the samples as compared to annealed, unimplanted samples. A comparison of flash and furnace annealing was made.
    Materialart: Digitale Medien
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