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  • 1990-1994  (1)
  • 1985-1989  (4)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 93 (1989), S. 6676-6681 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1200-1208 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Bodenstein approximation for trace-level intermediates is used to reduce multistep reaction-kinetic networks of arbitrary topology and size to simpler forms with only pseudosingle steps between nodes and to derive explicit equations for formation or consumption rates of end members. Networks with nontrace intermediates or steps of higher orders in intermediates must be broken at the respective steps into portions to which the procedure can then be applied separately. A recipe is provided with which rate and yield-ratio equations are readily compiled for networks of arbitrary configuration and complexity. The method is illustrated with an example of a reaction of industrial interest.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 690-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 75-87 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The concepts of coherence and composition paths, originally developed for multicomponent chromatography, are used to establish a simple theory of transport in systems with precipitation and dissolution in the course of multicomponent, single-phase flow in permeable media. Composition route construction in phase diagrams in combination with distance-time diagrams yields concentration profiles without recourse to trial-and-error procedurs. Detailed results are given for systems with three ions A, B, and X and up to two precipitates AX and BX. The extension to systems with additional, nonprecipitating species is described. The new approach confirms most conclusions of Bryant's earlier theory, removes assumptions stipulated in the latter, and is simpler to handle.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1615-1626 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The multicomponent equilibrium theory for ion-exchange columns (chromatography) has been extended to systems accompanied by reactions in either or both phases. Based on the concept of coherence of concentration waves in the original theory, the proposed approach includes a systematic way to determine the thermodynamic variance and a general mathematical formulation to construct the composition path grid by means of numerical techniques. With proper adjustments, this approach can be applied as well to adsorption columns involving reactions. As a practical example, a comparison of predicted and observed effluent histories for an anion-exchange system with dissociation-association reactions is shown.
    Type of Medium: Electronic Resource
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