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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Journal of the American Chemical Society 76 (1954), S. 2283-2284 
    ISSN: 1520-5126
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 37 (1986), S. 245-270 
    ISSN: 0066-426X
    Quelle: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 6940-6942 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: We report molecular dynamics simulations of n-butane at the B1 state point of Ryckaert and Bellemans [Chem. Phys. Lett. 30, 23 (1975); Discuss. Chem. Soc. 6, 695 (1978)]. The results confirm those of Edberg et al. (preceding paper) in that we found 58.5±1.0% of the molecules in the trans state as opposed to the value of 54% reported by Ryckaert and Bellemans.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 21 (1979), S. 659-667 
    ISSN: 1572-9613
    Schlagwort(e): Ornstein-Zernike equation ; Baxter's factorization ; softcore ; Yukawa closure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A model for simple fluids is proposed in which the radial distribution function has a parametric form appropriate to a soft-core fluid for interparticle separationr ⩽ R, whereR is some range parameter. Forr 〉 R, the direct correlation function is assumed to be of Yukawa form. The Ornstein-Zernike equation is solved for this system, yielding the radial distribution and the total correlation function for the entire range of interparticle separation. Methods of relating the model fluid to a real fluid by assigning values to the parameters are discussed.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 43 (1986), S. 621-643 
    ISSN: 1572-9613
    Schlagwort(e): Wetting transition ; exact solution ; random walk ; S.O.S. model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A model of a binary mixture, showing a wetting transition, is examined. No prewetting phenomena are found. The scaling functions are obtained for the film thickness and for the correlation lengths.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 50 (1988), S. 813-838 
    ISSN: 1572-9613
    Schlagwort(e): Spherical model ; Coulombic systems ; correlation function decay ; Stillinger-Lovett relations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We consider simple cubic lattice systemsΛ ind dimensions with a continuous real charge variableq(n) at each lattice siten. These variables are subject t'o a mean spherical constraint forcing 〈∑n∈Λ q 2(n)〉=‖Λ‖Q 2, where ‖Λ‖ is the number of lattice sites inΛ andQ is an elementary charge. The energy of the charges comes from interactions with an electrostatic potential, which is the solution of a symmetric second-difference Poisson equation on the lattice. Two cases are considered, both of which allow the inclusion of the effects of a fixed, constant, external electric field. On the latticeΛ 1=[1,N]⊗d , a Neumann condition is imposed at the surface of the lattice. The latticeΛ 2=[1,N]⊗ [−M,M]⊗(d−1) is periodic in each direction ranging over [−M, M] and has a Dirichlet condition imposed at the other two surfaces. OnΛ 2 a finite electric field may be applied, while onΛ 2 a finite potential difference may be applied across the lattice. The models are exactly solvable. We study the distribution functions on each system and show that they satisfy appropriate forms of the first two Stillinger-Lovett moment conditions. The two charge distribution functions show screening behavior at high temperature and extreme short range at an intermediate temperatureT 0(d), and oscillate as they decay to zero forT〈T 0(d). Because of the continuous nature of the charge variables, there is no Kosterlitz-Thouless transition in two dimensions. In three dimensions the change in the decay behavior of the distribution functions atT〈T 0(d) is precursor to a phase transition to a charge ordered state.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Communications in mathematical physics 40 (1975), S. 197-213 
    ISSN: 1432-0916
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik , Physik
    Notizen: Abstract The thermodynamic limit is taken using a sequence of regions all the same shape as a given region ω of volume |ω|, with a specified distribution of normal field component on ∂ω. We show that with magnetostatic interactions the limiting free energy density is bounded above by jhen where $$\bar f$$ (ϱ,B) is the free energy density for a system of density ϱ in a uniform external fieldB and the “inf” is taken over all divergence-free fieldsB with given normal component on ∂ω and all densities ϱ(x) compatible with particle number constraints of the form $$\int\limits_{\Gamma _i } {\varrho (x)d^3 x = \left| {\Gamma _i } \right|\varrho _i } $$ where Γi is a sub-region of ω. A physical argument suggests that this upper bound is the true thermodynamic limit, and that it takes account demagnetization effects. Electrostatic interactions can be treated similarly.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 17 (1977), S. 47-60 
    ISSN: 1572-9613
    Schlagwort(e): Surface phase transitions ; adsorption isotherms ; dense fluids
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We derive adsorption isotherms for an adsorbate of hard-sphere particles with “sticky” interactions at any fluid density being adsorbed onto a plane, “sticky” surface. The theory is based on the Percus-Yevick theory for bulk fluids and explicitly includes the equilibrium between the adsorbed fluid and the bulk adsorbate. The theory predicts a surface condensation at low temperatures and low bulk densities in good agreement with surface condensations found in experimental studies of adsorption of gases onto graphite. An approximate law of corresponding states for these transitions is developed. At higher bulk densities and room temperatures, the adsorption isotherms can show a maximum, in accord with recent experimental work.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 46 (1987), S. 179-190 
    ISSN: 1572-9613
    Schlagwort(e): Dipoles ; boundary conditions ; electrostatics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A microscopic derivation using the average Maxwell electric field is given for fluctuation formulas for the dielectric constant of a simulation sample for both periodic and reaction field boundary conditions. The reaction field case is for a spherical cavity reaction field. The derivations put both boundary conditions on an equal footing of microscopic theory and the only nonrigorous part of the derivation is the assumption that the region used to average the electric field is large enough. The fluctuation formula for reaction field boundary conditions is rather different from that used heretofore. The method is applied to a subregion of an isolated spherical system.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 55 (1989), S. 127-139 
    ISSN: 1572-9613
    Schlagwort(e): Spherical model ; Coulombic systems ; correlation function decay ; surface properties
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Studies of the mean spherical model with Coulomb interactions are continued, by considering a system on ad-dimensional lattice which is periodic ind−1 dimensions and has a free surface in the remaining dimension. It is shown explicitly that correlations along the free surface decay asy −d ind dimensions and show that the surface properties of this model are those expected for a charged system in its plasma phase.
    Materialart: Digitale Medien
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