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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 163-166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 1105-1124 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The curing exotherm pattern is affected by the equivalent ratio of curing agent, boron trifluoride monoethylamine complex (BF3 · MEA), to epoxy resin. The diglycidyl ether of 9,9-bis(4-hydroxyphenyl) fluorene (DGEBF) cures more slowly than the diglycidyl ether of bisphenol A (Epon 828). The glass transition temperatures (Tg's) of BF3 · MEA cured Epon 828 are increased with inceasing concentration of curing agent (0.0450-0.1350 eq.) cured DGEBF. The activation energies for the thermal decomposition for BF3 · MEA (0.0450-0.1350 eq.) cured DGEBF. The activation energies for the thermal decomposition for BF3 · MEA (0.0450 eq./epoxy eq.) cured Epon 828 and DGEBF are almost equivalent 43 and 44 kcal/mol, respectively. DGEBF when added to DGEBA improves the Tg and char yield with the BF3 · MEA curing system. The Tg of both resin systems can be increased by longer post cure, whereas the char yield does not appear to change significantly. No ester group formation is found for the BF3 · MEA-cured DGEBF, although this has been previously reported for the DGEBA system. The BF3 · MEA cure at 120°C is better than at 140°C because of vaporization and degradation of the curing agent at the higher temperature. The rapid gelation of the epoxy resin may be another reason for the lower degree of cure at high temperature.
    Additional Material: 25 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 75-85 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new route to prepare optically active polyamides was established, based on the polycondensation of two new active diesters: the active diesters of 4-chloro-1 hydroxybenzotriazole, such as 1,1'-(terephthaloyldioxy)bis(4-chloro-benzotriazole), and 1,1'-(isophthaloyldioxy)bis(4-chlorobenzotriazole), with optically active isomers of 2,4-diaminopentane. Dipolar aprotic solvents such as N,N-dimethylformamide and dimethyl sulfoxide were used as reaction solvents. The solution polycondensation carried out in solution at room temperature afforded optically active polyamides. The aminolysis of the two active diesters was carried out as a model reaction study.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 167-171 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 373-388 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polynucleotide analogs with a polyethylenimine backbone and optically active thymine- and adenine-containing pendants and their model compounds were synthesized. The pendants were prepared by the addition reaction of the nucleic acid base to ethyl crotonate. The ammonium salt of 3-(adenin-9-yl)butyric acid was employed to replace its free acid for the formation of diastereomeric salt with brucine. Fractional crystallization of the diastereomeric salt generates the partially resolved enantiomers. The solubility difference between the racemic mixture and its enantiomer was utilized to obtain the pure enantiomers. The active esters of the pendants were prepared. Grafting reactions were carried out by the reaction of active esters with PEI at room temperature. Completely grafted polymers were obtained.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 127-136 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radicals formed in poly(methyl methacrylate) (PMMA) under vacuum by UV irradiation at room temperature were carefully examined from 77 K to 300 K by electron spin resonance (ESR). The conventional nine-line spectrum was observed with significant overall intensity changes in contrast to previous reports. The intensity decreases greatly as the temperature increases from 77 K to 100 K. The intensity of the ESR spectrum increases as the temperature increases gradually from 100 K to 260 K. The spectral changes were reversible at all temperatures. Three different models are considered to interpret the temperature dependence of the intensity of the ESR spectrum. The results indicate that the ESR spectrum depends on (1) the steady-state concentration of the propagating radical in the polymer, (2) the conformational distributions of the radicals, and (3) the environmental structures of the polymer matrix.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 389-403 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polynucleotide analogs consisting of poly(vinylamine) as the backbone and optically active thymine and adenine derivatives as the pendants were synthesized. The pendants were prepared by the addition reaction of the nucleic acid base to ethyl crotonate followed by hydrolysis. The pendants were resolved using brucine as the resolving agent and an acetone-water mixture as the fractional crystallization solvent. The active esters of the pendants also were prepared. Poly(vinylamine) was isolated from water employing a weak acid, N-hydroxysuccinimide (HOSu), to protect the amino group of the poly(vinylamine). Model reactions for grafting were examined. Grafting reactions were carried out by reacting the active esters with the PVAm.6HOSu complex at room temperature.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 24 (1986), S. 627-630 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 69-76 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mechanical properties, deformation modes under both uniaxial tension and compression, low temperature mechanical relaxation behavior, and resistance to fracture under dynamic loading have been investigated for a medium impact grade of polystyrene, Shear yielding is the dominant mode of plastic deformation in compression while matrix crazing, together with some tearing and cavitation of the rubber phase, occurs in tension. The craze microstructure, as determined by transmission electron microscopy (TEM), is typical of that noted in polystyrene, with sharp craze-bulk interfaces and a characteristic midrib section. The presence of a third phase, possibly a processing aid, is evident in the TEM scans and in the dynamic mechanical data. The present data, together with the data obtained on polystyrene and on high impact polystyrene, are used to show the strong influence of rubber content on various mechanical properties, such as the tensile craze yielding stress, ductility, compression yield strength, degree of strain softening, and fatigue durability.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 23 (1985), S. 345-348 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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