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Retention of catechols in capillary electrophoresis with micellar and mixed micellar solutions (1989)

Wallingford, Ross A. ; Curry, Paul D. ; Ewing, Andrew G.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Microcolumn Separations 1 (1989), S. 23-27

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Details

ISSN: 1040-7685

Keywords: capillary ; electrophoresis ; micelles ; mixed micelles ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Zone electrophoresis in capillaries filled with micellar and mixed micellar solutions was examined for the separation of borate-complexed catechols. The mechanism for solute velocity was shown to involve both retention by hydrophobic interaction with the micelles and electrophoretic mobility. Mixed micellar systems involving SDS and SOS surfactants were shown to allow greater selectivity and increased separation efficiency.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mcs.1220010107

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