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  • 1
    Electronic Resource
    Electronic Resource
    Fracture toughness and crack instability in tough polymers under plane strain conditions (1987)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1128-1136 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The plane strain fracture toughness and fracture mechanisms of several tough engineering plastics have been studied and compared with poly(methyl methacrylate) (PMMA), a relatively brittle polymer. The tough polymers all are observed to form a multiple craze zone at the crack tip, which is shown to be the primary source of plane strain fracture toughness in these materials. The multiple craze zone is retained during slow crack growth but is metastable, and at a critical stress intensity and associated crack velocity, the system passes through a transition to a greatly accelerated single craze mode of unstable propagation.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760271504
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  • 2
    Electronic Resource
    Electronic Resource
    Structure-Property-Processing relationships of polyurethane-polyester interpenetrating polymer networks (1989)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 397-404 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interpenetrating polymer networks of polyurethane and unsaturated polyester were prepared by reaction injection molding (RIM) and transfer molding. The structures of the molded samples were analyzed by electron microscopy and dynamic mechanical analysis. It was found that polymer morphology and dynamic mechanical properties depend strongly on the molding temperature, reaction rate and reaction sequence. Simplified structure models based on Takayanagi's model and sample morphology can predict the storage modulus reasonably well but not the tanδ.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760290608
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  • 3
    Electronic Resource
    Electronic Resource
    Comparison of thermal and infrared spectroscopic analyses in the formation of polyurethane, unsaturated polyester, and their blends (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 1325-1342 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Differential scanning calorimetry (DSC) and infrared spectroscopy (IR) are two widely used techniques for the measurement of polymerization kinetics. Reactions of several thermoset polymers: a polyurethane, two unsaturated polyester resins, and polyurethane-polyester blends, were measured by these two methods. Results indicate that the thermal method is easy to use, and can generate both kinetic and thermal information. It is, however, less accurate and cannot detect detailed reaction mechanisms because the measurement relies upon the overall heat generation during reaction. Fourier transform infrared (FTIR) spectroscopy, on the other hand, can provide detailed kinetic information for multicomponent reactions such as styreneunsaturated polyester and polyurethane-polyester blends. Data analysis, however, is more tedious and requires reliable calibration. For an accurate kinetic measurement, both methods should be used because the results from both experiments can calibrate each other.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070360607
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  • 4
    Electronic Resource
    Electronic Resource
    Mixing characteristics of urethane based materials and polyurea in RIM (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 251-266 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To facilitate the study of new reaction injection molding (RIM) materials on a practical scale, a lab-scale mini-RIM machine was constructed. This machine is capable of delivering up to approximately 250 cc of material at rates of up to 125 cc/s. The RIM machine was first tested with conventional materials such as crosslinked and linear polyurethanes. The effect of varying the nozzle Reynolds number upon the adiabatic temperature rise corresponded to the results reported in previous works. Following this verification, two developmental materials, a polyurethane/polyester interpenetrating polymer network and a polyurea, were examined. The polyurea material showed a very strong dependency on mixing up to a Reynolds number above 400. The 75/25 PU/PEster reaction exotherms also showed a dependency upon mixing. However, this dependency is noticeable only in the polyester portion of the reaction, which can be attributed to the mixing sensitivity of the redox-type initiators used.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070370120
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  • 5
    Electronic Resource
    Electronic Resource
    Processing of polyurethane-polyester interpenetrating polymer network (IPN) (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 1157-1176 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics and heat transfer during the curing of a polyurethane-polyester interpenetrating polymer network (IPN) were investigated experimentally and theoretically. A model based on the additivity rule of constituent ingredients was used to predict the IPNs reaction kinetics and heat transfer. Compared with the adiabatic temperature rise measured during reaction injection molding and the temperature profiles measured during a casting process, the model prediction is close to the experimental data. Deviations of model prediction from experimental results were found in the comparison of reaction rate profiles measured by differential scanning calorimetry. This suggests that reaction interactions may exist in the polymerization system.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070360517
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  • 6
    Electronic Resource
    Electronic Resource
    General behavior of dilute binary solutions (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1391-1393 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330817
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  • 7
    Electronic Resource
    Electronic Resource
    Errata (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 170-170 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340125
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  • 8
    Electronic Resource
    Electronic Resource
    Kinetics of free radical polymerizations in reactive polymer processing (1985)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1585-1593 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic model has been developed for radical chain growth type of reactive polymer processing operations. This model incorporates considerations of the molecular diffusion that is described by a free volume theory and the basic reaction mechanism of the free-radical chain polymerization. Experimental results from the bulk styrene polymerization and a reaction of sheet molding compound (SMC) showed good agreement with the model.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690311002
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  • 9
    Electronic Resource
    Electronic Resource
    Process control of profile extrusion using thermal method. Part II: Closed loop control (1988)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 708-717 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The analytical flow model developed in Part I was applied to the online control of profile extrusion. A rubberized polystyrene was extruded through a simple L-shaped profile die with one thin section and one thick section. Take-up speed was used to control the size of the extrudate, and die temperature was used to control the shape of the extrudate. Two different control algorithms, a dual single-loop feedback PI controller and a multivariable feedforward plus feedback control method (FFC), were carried out for set point changes of the extrudate shape and size, and load disturbances of screw speed. Results showed that the PI feedback controller was satisfactory for long-term set point changes but not for load changes. The FFC worked well for load disturbances lower than 10 cycles/min. Owing to the slow dynamic response of die temperature, the shape loop can only be controlled for long-term disturbances.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760281103
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  • 10
    Electronic Resource
    Electronic Resource
    Reaction injection molding of polyureas I. Kinetics study (1988)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 955-963 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summarized in this paper are the experimental results and mathematical modeling of processing of polyureas. The experimental part includes the applications of solution polymerization to study the reaction kinetics of polyureas. The theoretical part includes a kinetic and heat transfer model that can apply solution polymerization data to predict the bulk polymerization of polyurea in the reaction injection molding process.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760281504
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