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Digitale Medien

Reaction of CF3 radicals with C2H6 (1986)

Arican, Haluk ; Arthur, Neville L.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 18 (1986), S. 437-443

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The hydrogen transfer reaction between C2H6 and CF3 radicals, generated by the photolysis of CF3I, has been studied in the temperature range 298-617 K. The rate constant, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, is given by \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_2 = (11.90 \pm 0.09) - (33230 \pm 740)/19.145T $$\end{document} where k2 is in cm3 mol-1 s-1 and E is in J mol-1. These results are compared with those previously reported, and the following best value for k2 is recommended: \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_2 = (11.94 \pm 0.07) - (33670 \pm 540)/19.145T $$\end{document}

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550180403

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