ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The formation of mullite via gels prepared from technical ethyl silicate and aluminium chlorides has been studied. Normally, gels prepared specifically with the oxide stoichiometry of mullite (3Al2O3·2SiO2) do not form the mineral mullite on firing to 1200° C in the absence of a mineralizer. However, when the stoichiometric gel is homogeneous (achieved by acidic or neutral catalysts during the gel preparation) firing at 1200° C can lead to an almost quantitative yield of mullite. For a homogeneous gel, the presence of strontium or caesium salts, or an organo-tin compound such as dibutyltin diacetate or dibutyltin oxide during the gel preparation promotes almost quantitative conversion to mullite at about 1000° C. There is a threshold concentration under which conversion to mullite is incomplete, some cristobalite being formed. For the organo-tin compounds, the type of aluminium chloride is unimportant and the way in which water for the hydrolysis step is added is also unimportant. When the gel is non-homogeneous, the product obtained on firing contains cristobalite andα-alumina orγ-alumina, with little mullite, even if strontium or caesium salts, or organ-otin compounds are present. A ceramic bond is formed from alumina and some other refractory grains during firing.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00555283
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