Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
91 (1989), S. 6579-6587
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Time evolution of a persistent hole spectrum has been investigated for dyes doped in polyvinyl alcohol films at 2 K. The zero-phonon hole profile measured for resorufin using a single-mode dye laser has been found to be nearly Lorentzian even in the case of relatively deep holes. The observed fluence-dependent depth and width of the zero-phonon hole are reproduced well by the numerical simulation based on a dispersive burning-kinetics model. It is pointed out that a large distribution of the burning rate is responsible for the fluence-dependent hole broadening. Time evolution of the phonon-sideband hole simulated using the same model is also compared with the experimental data. It is shown that the low-energy sideband hole is enhanced when the burning kinetics is dispersive.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.457376
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