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  • 1985-1989  (3)
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  • 1
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Wire-shaped nickel-based amorphous alloys exhibiting high strength and good ductility combined with a high corrosion resistance were produced for Ni-Pd-Si and Ni-Pd-P alloys by melt spinning in rotating water. The amorphous wires were formed over a relatively wide range from 29 to 82 at % palladium for (Ni-Pd)82Si18 alloys and from 12 to 52 at % palladium for (Ni-Pd)80P20 alloys. The Ni-Pd-Metalloid amorphous wires had a circular cross-section and smooth surface, and their diameters were 80 to 150μm. With increasing nickel content, their tensile strength, σf, increased from 1340 to 1710 MPa and the elongation to fracture, εf, decreased slightly from 2.2% to 1.9%. Cold-drawing the wires was an easy technique to reduce their diameter and to increase σf and εf up to an appropriate value of reduction in diameter. In addition, it is also effective in smoothing the wire surface. Their corrosion resistance was assumed to be sufficiently high since their polarization behaviour in 1 N H2SO4 solution was similar to palladium metal. Cold-drawing did not enhance corrosion and rather decreased apparently the active dissolution current density of some alloys owing to smoothing of the surface.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract By utilizing the characteristics of amorphous alloys capable of possessing specific electrocatalytic activity and corrosion resistance by alloying and surface activation treatment, an attempt was made to find amorphous alloys which are active as the anode material for production of sodium hypochlorite by electrolysis of seawater. Amorphous Ni-Nb and Ni-Ta alloys containing only 0.5–2.0 at % palladium and other platinum group metals showed a very high activity for chlorine production by electrolysis of 0.5M NaCl at 30°C when they were previously immersed in 46% HF for surface activation. The current efficiency of these surface-activated alloys for chlorine evolution considerably exceeded that of the currently used, most active Pt-Ir/Ti electrode for electrolysis of seawater. The surface activation treatment resulted in preferential dissolution of alloy constituents unnecessary for the electrocatalytic activity, i.e. nickel and valve metals, with a consequent enrichment of electrocatalytically active platinum group elements in the surface-activated layer. The corrosion weight loss of the surface-activated amorphous alloys under the steady state conditions for chlorine production was undetectable by a microbalance.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 16 (1986), S. 565-574 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The anodic characteristics of a variety of amorphous palladium-base alloys were examined with a view to their use for the production of sodium hypochlorite by electrolysis of dilute sodium chloride solutions at ambient temperature. The corrosion resistance of palladium-metalloid alloys was obtained by alloying with platinum group metals and/or valve metals. Among these alloys, rhodium-containing alloys showed high electrocatalytic activities for chlorine evolution. Surface activation treatment was, however, necessary to obtain sufficiently high activities for chlorine evolution at low overpotentials. Surface-activated amorphous alloys possessed considerably higher current efficiency for chlorine evolution in comparison with currently used anodes.
    Type of Medium: Electronic Resource
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