ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Complexes of manganese(II) with the tridentate oxime ligand 2,6-diacetylpyridine dioxime (H2dapd) have been synthesized and characterized. The complexes [Mn(H2dapd)X2] are pentacoordinate for X = Cl, Br or I but apparently octahedralvia bridging anions for X = NCS or NCSe. The complex [Mn(H2dapd)(NO3)2] adopts an octahedral structure involving monodentate and bidentate coordination of nitro groups. The complexes [Mn(H2dapd)2]X2 (X = Cl, Br, I, NO3, NCS or NCSe) involve an octahedral cation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00621081
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