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  • 1985-1989  (9)
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 90 (1986), S. 569-575 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 25 (1986), S. 898-900 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 27 (1988), S. 4509-4511 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 33 (1985), S. 15-49 
    ISSN: 1573-1472
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The influence of low surface roughness of deserts on the July circulation is examined by employing numerical simulations with a GLAS GCM. Two identical sets of simulations were made with the model starting from the initial state of the atmosphere based on the NMC analysis of observations for June 15, at OOZ for the years 1979 and 1980. The first set, called the Control, had land surface roughness set to 45 cm, everywhere. The second set called the Experiment, had surface roughness set to 0.02 cm for deserts, but 45 cm everywhere else on land. All other prescribed boundary conditions were the same in both runs. A comparative analysis of these simulations showed that the rainfall in the Sahara desert was reduced significantly in both Experiments as compared to the corresponding Controls; the ITCZ (inter-tropical convergence zone) moved southward, to about 14° N, which is close to its observed location at about 10° N. This was primarily caused by the relative moisture divergence from the smoother Sahara. In other deserts, which anyway had little rainfall in the July simulation of the Control run, there was virtually no change. The differences in regional heat and moisture budgets, particularly for the Sahara desert, are significant as compared to the sample standard deviation for a set of three July simulations (i.e., Control runs for three different initial conditions). In a third simulation, in which the surface roughness was changed over all land, similar results were obtained in the Sahara desert region. The study reveals the influence of low surface-roughness of deserts on the July rainfall. For the Sahara desert, this influence is comparable to that of an increase in surface albedo. In nature, formation of deserts leads to reduction of surface roughness as the vegetation perishes and soil erosion ensues. It is inferred that the smoothness of land then causes reduction in rainfall and further promotes desertification.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 375-380 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Raman spectrum of sulphonated copper phthalocyanine on a silver electrode surface is reported for four excitation wavelengths in the Q-band region at voltages between +0.6 and -0.6 V (vs SCE). SERS activity is observed and the bonding and orientation of the surface species are voltage dependent and are inferred from a vibrational analysis. Maximum scattering intensity is observed at -0.2 V (vs SCE) and is attributed to molecules bonded edge-on to the surface through SO3- groups.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 595-600 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance excitation profiles have been obtained for cobalt phthalecyanine at both room temperature and 10 K using a compressed disc of silver and the phthalocyanine. Low-frequency vibrations are shown to be influenced mainly by displacements on the bonding nitrogen, but high-frequency vibrations show a more complex pattern with some evidence that the vibrations v3 and v28 depend on Cα displacements. By comparison with copper, there appears to be a greater degree of scattering from 0-0 and 0-1 transitions and there is a shift towards increase 0-0 scattering in the sharper low-temperature profiles. It is concluded that a distortion, dynamic at room temperature and static at low temperature, plays a key role in determining the relative scattering and this distortion is larger for copper phthalocyanine than for cobalt phthalocyanine.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 31-34 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman excitation profiles for a substituted phthalocyanine dispersed as a polycrystalline powder in a silver disc were compared with those for a Langmuir-Blodgett (LB) multilayer of the same material on a silicon surface. There is a strong angular dependence of the efficiency of the scattering process. The LB profiles are strongly influenced by the electronic fields from the smooth semiconducting silicon surface, which gives rise to increased π-π* energy separation and comparatively efficient scattering from upper vibronic states.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 18 (1987), S. 277-279 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Mounting a sodium nitrate crystal on the surface of a disc made by compacting silver powder and the material to be studied enables Raman spectra of compounds such as zinc and nickel phthalocyanine to be measured in such a way that relative peak inteasities in any one disc can be quantified using the nitrate as a standard. It is a good method for the measurement of low-temperature spectra of resonant compounds and for the measurement of temperature dependence.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 16 (1985), S. 245-250 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Compacted discs prepared from a mixture of finely divided particles of a compound diluted in a large excess of metal powder facilitate the measurement of Raman spectra for some compounds which give poor scattering by conventional techniques. The method is most useful with coloured compounds. The advantages include simplicity, increased signal-to-noise ratio by factors of up to 1000 and decreased or altered fluorescence. The effect appears to be caused mainly by small crevices in the compacted metal surface which act as internal mirrors to produce many small multiple-reflection cells, but there is also evidence of an electronic interaction with the metal surface. Silver, aluminium and copper matrices were studied, silver being found to be the most advantageous, although aluminium under certain conditions may also be effective.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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