ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions An efficient method for the synthesis of α,α,ω-trihydropolyfluoroalkyl chlorophosphates is by reacting α,α,ω-trihydropolyfluoroalkyl dichlorophosphites and bis-(α,α,ω-trihydropolyfluoroalkyl) phosphites with sulfuryl chloride. It has been found that in three-coordinated polyfluoroalkyl phosphites, the high electronegativity of the polyfluoroalkyl groups hinders cleavage of the latter on reaction with sulfuryl chloride, thereby facilitating the formation of oxidation products.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00962673
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