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  • 2000-2004  (1)
  • 1980-1984  (3)
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  • 1
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 117 (2002), S. 3132-3138 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The first and second bond dissociation enthalpies of H2S have been investigated at up to the CCSD(T)/aug-ccpV6Z level of theory. Corrections for core/valence electron correlation, anharmonic zero point vibrational energy and relativistic effects were followed by extrapolation to the complete basis set limit. Analysis of direct dissociation yields D0(S–H)=349.9 and D0(HS–H)=375.8 kJ mol−1. Together these imply an atomization enthalpy for H2S about 1 kJ mol−1 larger than literature evaluations. Consideration of exchange of a second H atom from OH to SH yields D0(HS–H)=376.2 kJ mol−1. The two computations of D0(HS–H) lie within 0.5 kJ mol−1 of a recent spectroscopic measurement of D0(HS–H)=376.24±0.05 kJ mol−1 [R. C. Shiell, X. K. Hu, Q. J. Hu, and J. W. Hepburn, J. Phys. Chem. A 104, 4339 (2000)]. The deuterated analogs SD and D2S are also considered. There is also accord to within 1.5 kJ mol−1 with D0(S–H)=348.4±0.8 kJ mol−1, which we derive from the experimental literature. We propose revised enthalpies of formation, ΔfH0(2Π3/2SH)=142.6±0.8 kJ mol−1 and ΔfH298.15(SH)=143.1±0.8 kJ mol−1. The results suggest the dominant uncertainties in these high-level calculations come from the basis set extrapolation and scalar relativistic terms, and that both contribute about 1 kJ mol−1 uncertainty. We also obtain D0(H–OH)=492.6 kJ mol−1, which compares well with recent experiments. © 2002 American Institute of Physics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of molecular histology 16 (1984), S. 793-797 
    ISSN: 1573-6865
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of molecular histology 16 (1984), S. 211-218 
    ISSN: 1573-6865
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 59 (1981), S. 465-471 
    ISSN: 1573-5036
    Schlagwort(e): Ectomycorrhiza ; Flooding ; Michigan ; Peat ; Phosphorus ; Salix
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Willows growing in a north central Michigan wetland were found to be ectomycorrhizal throughout the 1978 growing season on each of two sites (one water-saturated, one relatively drier). Each site was dominated by a mix of sedges (Carex spp.) and willows (Salix spp.). On both sites, phosphorus was added at two levels (20 or 200 kg P ha−1) to simulate potential inputs from the disposal of secondarily-treated municipal wastewater. The intensity of willow root infection was determined by scoring root tips on a 0 to 4 scale based on mantle-, intercellular hyphae-, and root epidermal cell characteristics. Infection on the wet site remained uniformly heavy in July and August when P was added, but it declined significantly during August for control plants at both sites. When water levels increased during September, the intensity of mycorrhizal infection increased on control plants on the wet site. On the drier site, mycorrhizal intensity decreased on controls and on plants exposed to the highest P levels. Between August and September samplings, mycorrhizal intensity increased considerably on dry-site controls but did not change on plants exposed to added P.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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