ISSN:
0025-116X
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
A series of polymeric materials were prepared by reacting poly(2021840311vinylpyridine) or poly-(4-vinylpyridine) with ruthenium (III) chloride in refluxing methanol. Mole ratio of RuCl3 to vinylpyridine (Ru: PVP ratio) was varied from 2:1 to 1:20. From IR and UV/VIS spectroscopic data it is shown that several kinds of ruthenium-PVP complexes are present, their relative proportions depending on the Ru: PVP ratio of the original reaction mixture and on the reaction time. The spectroscopic properties of the polymer complexes are compared to those of methylpyridine complexes of ruthenium(III) chloride.
Zusätzliches Material:
6 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/macp.1983.021840316
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