ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The cluster compound H4[Ta6Cl12(CN)6] · 12H2O was prepared and identified by potentiometric titrations, i.r. and visible spectra and by three-dimensional single-crystal x-ray diffraction methods. Discrete [Ta6Cl12(CN)6]4− ions contain a linear Ta−C≡N unit with Ta−C=2.21(4) and C−N=1.16(5) Å, respectively. Each nitrogen atom is hydrogen bonded [2.63(12)Å] to two oxygen atoms.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618006
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