ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The complex [Bu 4 n N][Mo2O2Cl5(SPh)2] has been prepared by reaction of [Bu 4 n N][MoO(SPh)4] with stoichiometric amounts of HCl and characterised by single crystal X-ray structure analysis. The dimer is bridged by two oxo-groups and one chloride and each Mo has pseudo-octahedral co-ordination. The related compound [Mo2O3(SPh)2(S2CNMe2)2] was synthesised by reaction of [MoO2(S2CNMe2)2] with thiophenol in methanol and has also been characterised crystallographically. In this case the triple-bridge consists of two thiophenolate sulphurs and one oxo-group, each molybdenum having pseudo-octahedral geometry. These structures are compared with other triply-bridged species.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618709
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