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  • 1980-1984  (8)
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  • 1
    Electronic Resource
    Electronic Resource
    Die Kristallstruktur von Warikahnit, Zn3[(H2O)2|(AsO4)2] (1980)
    Springer
    Mineralogy and petrology 27 (1980), S. 187-199 
    Details
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Summary The crystal structure of the new mineral warikahnite, Zn3[(H2O)2|(AsO4)2], was determined from diffractometer data and refined toR=0,038 for 3428 observed independent reflections. Warikahnit is triclinic, $$P\bar 1$$ , witha=6.710(1),b=8.989(2),c=14.533(2) Å, α=105.59(1), β=93.44(1), γ=108.68(1)°,Z=4. The crystal structure of warikahnite contains 6 different coordination polyhedra of zinc with the coordination numbers 6,5 and 4 and with 5 different combinations of ligand. The hydrogen bonds are discussed on the basis of charge balance and IR spectra.
    Notes: Zusammenfassung Die Kristallstruktur des neuen Minerals Warikahnit, Zn3[(H2O)2|(AsO4)2], wurde mit Diffraktometerdaten bestimmt und bis zuR=0,038 für 3428 unabhängige Reflexe verfeinert. Warikahnit ist triklin, $$P\bar 1$$ , mita=6,710(1),b=8,989(2),c=14,533(2) Å, α=105,59(1), β=93,44(1), γ=108,68(1)°,Z=4. Die Kristallstruktur des Warikahnits enthält sechs unterschiedliche Koordinationspolyeder des Zinks mit den Koordinationszahlen 6, 5 und 4 und mit fünf verschiedenen Ligandenkombinationen. Die Wasserstoffbrückenbindungen werden mit Hilfe der Ladungsbilanz und des IR-Spektrums diskutiert.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01082368
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  • 2
    Electronic Resource
    Electronic Resource
    Über P-P-haltige cyclische Verbindungen. II (1984)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 508 (1984), S. 61-72 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On P—P Containing Cyclic Compounds. II.Reaction of N,N'-dimethylthiourea with phenyl dichlorophosphane yields 1.4-dimethyl-2. 3-diphenyl-1.4.2.3-diazadiphospholidine-5-thione-2-sulfide (II). The compound is characterized by its nmr, vibration and mass spectra as well as the results of an X-ray structural analysis. Byproduct of the reaction is N-(N,N'-dimethylcarbamimidoyl)-N,N'-dimethyl thiourea hydrochloride (III), which crystallizes with pyridinium chloride. Molecular and crystal structure are reported. With methyl dichlorophosphane N,N'-dimethylthiourea forms 1.2.3.4-tetramethyl-1.4.2.3-diazadiphospholidine-5-thione-2-sulfide (IV), which is characterized by its nmr and vibration spectra.
    Notes: Die Umsetzung zwischen N,N'-Dimethylthioharnstoff und Phenyldichlorphosphan führt zu 1,4-Dimethyl-2, 3-diphenyl-1, 4, 2, 3-diazadiphospholidin-5-thion-2-sulfid (II). Die Verbindung ist durch ihre NMR-, Schwingungs- und Massenspektren sowie die Ergebnisse einer Röntgenstrukturanalyse charakterisiert. Nebenprodukt der Umsetzung ist N-(N,N'-Dimethylcarbamimidoyl)-N,N'-dimethyl-thioharnstoffhydrochlorid (III), das mit Pyridiniumchlorid kristallisiert. Molekül- und Kristallstruktur werden mitgeteilt. Mit Methyldichlorphosphan bildet N,N'-Dimethylthioharnstoff 1,2,3,4-Tetramethyl-1,4,2,3-diazadiphospholidin-5-thion-2-sulfid (IV), das durch seine NMR- und Schwingungsspektren charakterisiert ist.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19845080110
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  • 3
    Electronic Resource
    Electronic Resource
    Imidodiphosphorsäuretetraphenylester, Salze und Komplexe (1983)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 496 (1983), S. 109-116 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tetraphenyl Imidodiphosphate, Salts, and ComplexesAn improved preparation of pure tetraphenyl imidodiphosphate and the preparation of the sodium, diethylammonium, barium and calcium salts of tetraphenyl imidodiphosphate are described. The syntheses of bis(tetraphenylimidodiphosphato)copper(II) and tris(tetraphenylimidodiphosphato)iron(III) are reported. The new compounds are characterized by their properties and nmr spectra. An X-ray crystal structure analysis is reported for the copper complex.
    Notes: Die verbesserte Reindarstellung des Imidodiphosphorsäuretetraphenylesters, die Darstellung seines Natrium-, Diethylammonium-, Barium- und Calciumsalzes sowie die von Bis(tetraphenyl-imidodiphosphato)-kupfer(II) und Tris(tetraphenyl-imidodiphosphato)-eisen(III) werden beschrieben. Die neuen Verbindungen sind durch ihre Eigenschaften und NMR-Spektren charakterisiert. Das Ergebnis der Röntgenstrukturanalyse von Bis(tetraphenyl-imidodiphosphato)-kupfer(II) wird mitgeteilt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19834960112
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  • 4
    Electronic Resource
    Electronic Resource
    Über Diazadiphosphetidine. III. N,N′-Diphosphoryl-diaza-λ3,λ3-diphosphetidineProfessor Werner Reif zum 60. Geburtstage am 24. September 1981 gewidmet. (1982)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 486 (1982), S. 177-186 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Diazadiphosphetidine. III. N,N′-Diphosphoryl Diaza-λ3,λ3-diphosphetidinesSynthesis, structure and mass spectrum of trans 1,3-bis(diethoxyphosphoryl)-2,4-bis(diethylamino)-1,3,2,4-diaza- λ3,λ3-diphosphetidine (I) are described. Furthermore the procedure for preparing bis(diethylamido)-phosphorous-(N-diethoxyphosphoryl)-imide (III) and 1,3-bis(diphenoxyphosphoryl)-2,4-bis(diethylamino)-1,3,2,4-diaza-λ3,λ3-diphosphetidine (VI) is presented. I, N-diethyl-N′N″-bis(diethoxyphosphoryl)-phosphorous triamide (II), III, VI and bis(diethylamido)-phosphorous(N-diphenoxyphosphoryl)-imide(VIII) are characterized by their nmr spectra.
    Notes: Synthese, Struktur und Massenspektrum von trans-1,3-Bis(diethoxyphosphoryl)-2,4-bis(diethylamino)-1,3,2,4-diaza-λ3,λ3-diphosphetidin (I) werden beschrieben. Weiter wird die Synthese von Bis(diethylamido)-phosphorigsäure-(N-diethoxyphosphoryl)-imid (III) und 1,3-Bis(diphenoxyphosphoryl)-2, 4-bis(diethylamino)-1,3,2,4-diaza-λ3,λ3-diphosphetidin (VI) mitgeteilt. I, N-Diethyl-N′,N″-bis(diethoxyphosphoryl)-phosphorigsäuretriamid (II), III, VI und Bis-(diethylamido)-phosphorigsäure-(N-diphenoxyphosphoryl)-imid (VIII) sind durch ihre Spektren charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19824860120
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  • 5
    Electronic Resource
    Electronic Resource
    AgCo3H2(AsO4)3 und AgZn3H2(AsO4)3 Darstellung und Kristallstruktur Ein weiterer neuer Arsenat-StrukturtypProfessor Josef Goubeau zum 80. Geburtstage am 31. März 1981 gewidmet (1981)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 474 (1981), S. 123-134 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: AgCo3H2(AsO4)3 and AgZn3H2(AsO4)3. Preparation and Crystal Structure. Another New Structure Type of an ArsenateAgCo3H2(AsO4)3 (1) and AgZn3H2(AsO4)3 (2) were prepared by heating of As2O5, AgNO3, CoSO4 · 7H2O, ZnSO4 · 7H2O, respectively, and water in a sealed tube at 300°C and investigated with X-rays. Both compounds are isotypic and crystallize in the monoclinic space group C2/c with 4 formula units per cell. The lattice parameters are (1): a = 1215.9(6), b = 1243.8(7), c = 678.2(3) pm, β = 113.16(3)° (2): a = 1216.9(2), b = 1249.5(3), c = 675.5(1) pm, β = 112.77(1)°. The structure contains chains of edge-shared CoO6 or ZnO6 octahedra, respectively, which are connected by AsO4 tetrahedra and silver oxygen ribbons with square planar coordinated silver forming a framework. Based on the charge balances derived from the geometrical data and the IR spectra the occurence of hydrogen bonds is discussed.
    Notes: AgCo3H2(AsO4)3 (1) und AgZn3H2(AsO4)3 (2) wurden durch Erhitzen eines Gemisches von As2O5, AgNO3, CoSO4 · 7H2O bzw. ZnSO4 · 7H2O und Wasser auf 300°C im Autoklaven dargestellt und röntgenographisch untersucht. Beide Verbindungen sind isotyp und kristallisieren in der monoklinen Raumgruppe C2/c mit 4 Formeleinheiten in der Elementarzelle. Die Gitterkonstanten sind: (1) a = 1215,9(6), b = 1243,8(7), c = 678,2(3) pm, β = 113,16(3)° (2) a = 1216,9(2), b = 1249,5(3), c = 675,5(1) pm,β = 112,77(1)°. Die Struktur enthält Ketten aus kantenverknüpften CoO6- bzw. ZnO6-Oktaedern, welche über AsO4-Tetraeder, sowie über Silber-Sauerstoff-Bänder mit quadratisch-planar koordiniertem Silber zu einem Gerüst verknüpft sind. Anhand der aus den geometrischen Daten berechneten Ladungsbilanzen und der IR-Spektren wird das Auftreten von Wasserstoffbrücken diskutiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19814740313
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  • 6
    Electronic Resource
    Electronic Resource
    N-Phenylquecksilber-N,N-bis(phosphorsäurediphenylester)-imidProfessor Rudolf Hoppe zum 60. Geburtstage gewidmet (1982)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 491 (1982), S. 266-270 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: N-Phenylmercury-N,N-bis(phosphoric diphenylester)imideSynthesis, properties, and structure of the title compound are described.
    Notes: Darstellung, Eigenschaften und Struktur der Titelverbindung werden beschrieben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19824910134
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  • 7
    Electronic Resource
    Electronic Resource
    Struktur und Reaktionen von Phosphorsäure-tris(N-dichlorphosphino-N-methylamid). Phosphorsäure-tris(N-phenylchlorphosphino-N-methylamid) (1982)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 486 (1982), S. 187-192 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structure and Reactions of Phosphoric tris(N-dichlorophosphino-N-methylamide). Phosphoric tris(N-phenylchlorophosphino-N-methylamide)The X-ray structural analysis of phosphoric tris(N-dichlorophosphino-N-methylamide), I, is reported. Synthesis, properties and nmr data of phosphoric tris(N-phenylchlorophosphino-N-methylamide), III, are described.
    Notes: Es wird die Röntgenstrukturanalyse von Phosphorsäure-tris(N-dichlorphosphino-N-methylamid), I, mitgeteilt. Die Synthese, Eigenschaften und NMR-Daten von Phosphorsäure-tris(N-phenylchlorphosphino-N-methylamid), III, sind beschrieben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19824860121
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  • 8
    Electronic Resource
    Electronic Resource
    Dimethylaminoalane, H3 - n Al[N(CH3)2]n, n = 1, 2, 3 Kristallstrukturen und Molekülspektren (1983)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 504 (1983), S. 67-76 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dimethylaminoalanes, H3 - nAl[N(CH3)2]n, n = 1, 2, 3; Crystal Structures and Molecular SpectraThe X-ray crystal structure analyses of dimethylaminoalane (I), bis(dimethylamino)alane, and tris(dimethylamino)alane are reported and the molecular spectra of these compounds are discussed. I is trimeric and exists as sixmembered ring of a chair-conformation. II and III are dimeric and build up planar four-membered rings.
    Notes: Es werden die Röntgenstrukturanalysen von Dimethylaminoalan (I), Bis(dimethylamino)alan (II) und Tris(dimethylamino)alan (III) mitgeteilt und deren Molekülspektren diskutiert. I ist trimer und liegt als Sechsring in der Sesselform vor; II und III sind dimer und bilden planare Vierringe aus.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19835040909
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