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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 80 (1984), S. 3-19 
    ISSN: 1573-5036
    Keywords: 15N Nitrogen balance ; Nitrogen fertilizer ; Nitrogen loss ; Phenyl phosphorodiamidate ; Sorghum bicolor L ; Urea ; Urea phosphate ; Urea supergranule
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary As part of a research program to determine the fate of N fertilizers applied to dryland sorghum in the semi-arid tropics,15N balance studies were conducted with various N sources in the greenhouse. Two American soils, Houston Black clay (Udic Pellustert) and Windthorst sandy loam (Udic Paleustalf), similar in properties to the Vertisol and Alfisol in the semi-arid tropics of India, were employed. Experiments were conducted with large pots containing 20 or 60 kg of soil which was subjected to several watering regimes. The15N not accounted for in the plant and soil was presumably lost. Losses of N on calcareous Houston Black clay were greatest for broadcast urea, 16%–28%. Amendment of broadcast urea with 2% phenyl phosphorodiamidate, a urease inhibitor, reduced N losses only slightly to 15%–20%. Point placement of urea at a 6 cm soil depth reduced losses to 1%–11%. Granule size had no effect on N loss from point-placed urea. Ammonia volatilization was apparently the main N loss mechanism, since N losses from sodium nitrate were less than 7%, except when the soil surface was waterlogged. N losses on the Windthorst soil averaged 30% from urea and 11% from ammonium nitrate. Amendment of urea with urea phosphate to form a 27% N and 13% P product reduced fertilizer N losses but did not increase grain yield on Windthorst soil. N losses were also less from ammonium nitrophosphate than from urea. Band and point placement of urea 6 cm below the soil surface were equally effective in reducing N loss on Houston Black clay. The findings give credence to the recommendation of deep band placement for urea in the semi-arid tropics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 1 (1980), S. 191-202 
    ISSN: 1573-0867
    Keywords: 15N ; rice soils ; urea fertilization ; ammonia volatilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Ammonia volatilization is an important mechanism of N loss from flooded rice soils. Inhibition of urease may delay the formation of conditions favorable to NH3 volatilization in the floodwater, thus giving the soil and plant a better chance to compete with the atmosphere as a sink for N. The experiments reported here were designed to identify the site of urea hydrolysis in flooded soils and to attempt selective urease inhibition with some of the inhibitors reported in the literature. Studies with three flooded soils using15N-labeled urea showed that 50–60% of the urea was found in the floodwater, despite incorporation. This floodwater urea is hydrolyzed largely at the soil—floodwater interface and subsequently returns to the floodwater (〉 80%) or is retained by the soil (〈 20%). Of the following urease inhibitors (K-ethyl-xanthate; 3 amino-1-H-1, 2, 4-triazole; phenylphosphorodiamidate) added at 2% (w/w of urea), only the latter was able to delay the appearance of NH3 (aq) in the flood-water and thus delay NH3 volatilization. Use of an algicide addition to the floodwater depressed NH3 (aq) levels during the entire period studied, but in the presence of PPD the algicide had little additional effect.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 324 (1982), S. 400-408 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorescence Quenching of N-Arylurethanes by KetonesFluorescence and photo-Fries reaction of N-aryl-urethanes can be quenched by diffusion-controlled energy transfer to biacetyl, acetone and other aliphatic ketones. Quenching of the photo reaction and fluorescence obeys the Stern- Volmer Equation.The efficiency of quenching may by influenced by solvents and substituents changing the S1 energies of donors and acceptors. The identical rate constants determined by independent methods demonstrate that quenching of urethane fluorescence and photoreaction by aliphatic ketones occurs completely by singlet energy transfer.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quenching of Excited Singlet States of N-Arylurethanes by Intra- and Intermolecular Resonance Energy Transfer to Salicylic Acid Esters and AmidesFluorescence and photo-Fries reactions of N-arylurethanes are quenched by energy transfer to salicylic acid esters and amides. Quenching of photo reaction and fluorescence obeys the Stern-Volmer equation and is accompanied by sensitization of salicylic acid ester fluorescence.The rate constants of energy transfer are greater than the diffusion rate constants and show that resonance energy transfer occurs.The influence of solvent viscosity, donor lifetime, and spectral overlap is discussed. The rate constants of energy transfer are slightly decreased by increasing the solvent viscosity.The results are in good agreement with the treatment of POVINELLI.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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