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  • Electronic Resource  (4)
  • 1980-1984  (2)
  • 1975-1979  (2)
Material
  • Electronic Resource  (4)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 43 (1978), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Complex formation of anthocyanins with other plant constituents and the resulting color intensification enhances the possibility of their use as naturally occurring food colorants. Anthocyanins representing the four pigment groups characteristic for Vitis species, e.g. malvidin-3-glucoside, malvidin-3-p-coumarylglucoside, malvidin-3,5-diglucoside and malvidin-3-p-coumarylglucoside-5-glucoside in the concentration range 4 X 10-6 to 4 X 10-3 M were investigated for complex formation in the presence of the flavonol glycoside rutin (0-2.4 X 10-2 M). The experiments performed under conditions similar to those existing in grape juice showed a maximum color intensification of 1000% with malvidin-3,5-diglucoside. A 44 nm shift in the absorption maximum was observed concurrently with color intensification. The ability of the investigated anthocyanins to form deeply colored complexes with rutin decreased in the following order: malvidin-3,5-diglucoside (1000%), malvidin-3-p-coumarylglucosid-5-glucoside (500%), malvidin-3-p-coumarylglucoside (490%) and malvidin-3-glucoside (145%).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 44 (1979), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Complex formation of anthocyanins with rutin stabilize their color under conditions similar to those of grape juices. This color intensification results in both the increase in intensity and a batho-chromic shift in the color of their solutions. The changes in the color intensity of the anthocyanin solutions are not uniform throughout the pH range 1–7, but are influenced by the substitution patterns of the B-ring, and by the nature of substituent in the 3- and 5-position. Thus maximum complex formation occurs with the 3-glucosides at around pH 4.2, with the 3,5-diglucoside at around pH 3.1, with the 3-acylglucosides around pH 4.0–4.5 and at around pH 3.1 with the 3-acylglucoside+glucosides: The obtained data further support the involvement of the anhydro base of anthocyanins in the complex formation with rutin in the pH range 1–7.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 37 (1981), S. 213-214 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Quercetin-7-neohesperidoside was prepared from eriodictyol 7-neohesperidoside by alkaline peroxide oxidation. Spectral properties of this compound and its derivatives are reported.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 38 (1982), S. 1030-1032 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Spectroscopic evidence shows that the flavylium cation (1) undergoes hydroxylation to form the carbinol base (2) and can also deprotonate to form the anhydro (quinonemethane) bases (3a and3b). The anhydro bases hydrate to the carbinol base. The carbinol base above pH 6, or the ionzed carbinol base (2a), undergoes diring fission to produce the cischalcone (4).
    Type of Medium: Electronic Resource
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