ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Characterization of Cyclohexasilane Si6H12A preparation route is described in detail for the first synthesis of Si6H12, starting from the full phenylated Si6-cycle. With the aid of AlCl3/HCl all phenyl groups are splitted off and the yielded Si6Cl12 is hydrogenated with LiAlH4. Si6H12 is characterized by means of different kinds of spectras and their properties.
Notes:
Es wird eine Darstellungsmethode für die erstmalige Synthese von Si6H12 aus dem perphenyliertem Si6-Ring ausführlich beschrieben, wobei man mittels AlCl3/HCl erst alle Phenylgruppen abspaltet und das entstandene Si6Cl12 mit LiAlH4 hydriert. Si6H12 wird durch verschiedene Spektren und seine Eigenschaften charakterisiert.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794590113
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