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  • 1975-1979  (2)
  • 1970-1974  (2)
Material
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Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 12 (1973), S. 1566-1572 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 18 (1977), S. 499-502 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 5 (1970), S. 104-110 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Summary The organophosphorus insecticide, methidathion, degraded rapidly in a sandy loam, silt loam, clay loam and organic soil. Fifty percent of the initial applications decomposed in less than 2 weeks and more than 90% of the insecticide disappeared within 16 weeks. When soils were treated with methidathion containing14C in the ring or methyl side chain 40 to 66% of the radioactivity was expired as14CO2 after 16 weeks. Over half of the remaining radioactivity could not be extracted from the soils while lesser amounts were recovered as the parent compound or as water-soluble degradation products. In fumigated soils 50% of the initial insecticide applications still remained after 16 weeks and less than 3% of the radioactivity was expired as14CO2 which suggests that microorganisms are primarily responsible for the degradation of methidathion in soil.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 8 (1979), S. 661-672 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract An enzyme which catalyzed the hydrolysis of crotoxyphos ((E)-1-phenylethyl 3-[(dimethoxyphosphinyl)oxy]-2-butenoate) was isolated from nonsterile and radiation-sterilized Chehalis clay loam with 1.5M Tris (2-(hydroxymethyl)-2-nitro-1,3-propanediol) and partially purified with lead acetate treatment. Two soil-g equivalents of lead acetate purified enzyme in pH 8 buffer hydrolyzed 0.13 μmol of substrate to dimethyl phosphate and α-methylbenzyl 3-hydroxycrotonate in 16 hr at 37°C. The enzyme exhibited maximal activity around pH 8.0 and was irreversibly inactivated below pH 5.0 or above pH 10.0. The Km value for crotoxyphos was calculated to be 4.63×10−3 M. The enzyme was stable at 60°C for 10 min, retained activity indefinitely at −10°C, and was completely inactivated within a week at room temperature. When applied to autoclaved Chehalis clay loam, purified enzyme lost 75% of its activity after one week and the remainder within two weeks.
    Type of Medium: Electronic Resource
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