Bibliothek

Notizen: The photodissociation of F2 in crystalline Kr is subject to only a minor cage effect—quantum yield of 0.5 at 308 nm, at T=12 K. Two-photon-induced harpooning in the same system leads to dissociation with near unit quantum efficiency; it is shown that this absorption is coherent with a giant cross section of 3(±2)×10−45 cm4 s at 275 nm. Excitation and emission spectra of charge-transfer transitions in solid Kr doped with F atoms, and solid Ar multiply doped with F/Kr are reported. The vertical excitation in F/Kr leads to a state delocalized over immediate neighbors—assigned to Kr+6F−. This state localizes on a subpicosecond time scale to the triatomic Kr+2F− configuration. The latter relaxes radiatively (τr=140 ns), to the repulsive wall of the ground state (∼1 eV above ground). The excitation in F:Kr/Ar solids shows the diatomic KrF(B←X) resonances. From the analysis of the spectrum, a harmonic frequency ω=75(±3) cm−1 is extracted for F atoms in the ground state, consistent with molecular-dynamics simulations of an octahedrally trapped F atom [ω=70(±1) cm−1]. The diatomic KrF(B) state relaxes on a time scale of 20 fs〈t〈500 fs to the mixed triatomic configuration, (ArKr)+F−, which then relaxes radiatively (τr=60 ns). The kinetic energy released upon the radiative dissociation of triatomic exciplexes generates acoustic waves, and defects, and leads to mass transport. The modes of propagation of the acoustic waves, their subsequent thermalization, and self-annealing of the solid, are directly monitored by spatially and temporally resolved transient scattering experiments. A transient loss (σ(approximately-equal-to)10−17 cm2), the origin of which is not fully understood, is observed for Kr2F isolated in solid Kr. The mass transport, and long-range migration of F atoms (∼10 lattice sites), is directly monitored in multiply doped Ar solids in which the shuttle of F atoms between Xe and Kr centers can be demonstrated.

Notizen: Vacuum scanning tunneling microscopy has been used to investigate the hydrogen-terminated Si(111) surfaces obtained upon dissolution of the native oxide in HF and NH4F solutions. Whereas etching in aqueous HF acid produces an atomically rough surface, comparable treatment in NH4F results in atomically flat surfaces. These atomically flat surfaces are extremely well ordered and exhibit terraces which extend thousands of angstroms.

Notizen: In the past, the doorstopper method has been used successfully for determining in situ tectonic stresses. Here an example is given about the application of the borehole slotter in the domain of tectonic stress determinations, which is an innovative strain relief technique without overcoring. Data are presented that test the reliability of the strain measurements by the borehole slotter under well-known stress conditions, that indicate the reproducibility of borehole slotter strain data compared with those from doorstopper measurements, and that demonstrate the utility of the borehole slotter even for the determination of weak tectonic strains. In northern Switzerland the borehole slotter was used in a horizontal borehole under lithostatic loading conditions only, in a rock slope area with very heterogeneous stress conditions, and in a vertical borehole where tectonic stress should be dominant. The results show that the borehole slotter is a reliable technique, which allows precise determination of in situ strains. In addition, borehole slotter measurements are less time-consuming and therefore less costly than most other stress-measuring techniques—an important aspect in a future of reduced research budgets.〈section xml:id="abs1-2"〉〈title type="main"〉SummaryThe borehole slotter is a strain relief technique, using a recoverable strain sensor that need not be glued to the rock surface and need not be overcored. It is quicker to use than most other stress or strain measuring techniques, especially in comparison to standard overcoring techniques (Fig. 14).The borehole slotter supplied convincing results with respect to principal stress orientations, in good agreement with:(i) principal stress orientations related to lithostatic stress conditions (Dittingen 2 site),(ii) palaeostress orientations during the main stage of Jura folding only 13 to 7 Ma (Laufen 1 site),(iii) the results of neighboring door-stopper measurements (Dittingen 1 site).The borehole slotter tests do not supply stress magnitudes directly. Thus, the elastic properties of the rock mass have to be determined independently. Stress ratios from borehole dotter tests in Dittingen 2 are realistic.In conclusion, the borehole slotter is a fully developed probe to measure in situ strains in boreholes. It allows the reliable determination of a large number of data within a short time even in weakly stressed rocks. This makes the borehole slotter a powerful tool for the determination of contemporary regional tectonic stress fields.

Notizen: Book Reviews

Notizen: Zusammenfassung Es wird die Einwirkung homogener Kathodenstrahlen im Geschwindigkeitsbereich von etwa 1 bis 50 kV auf normale Selenphotoelemente untersucht, um die beobachtbaren Erscheinungen zu Rückschlüssen auf die Struktur der Elemente und den quantitativen Ablauf des inneren Vorgangs zu verwerten. Es zeigt sich, daß das Verhalten der Elemente gegen Kathodenstrahlen, insbesondere die Abhängigkeit der Erscheinung von der Strahlgeschwindigkeit, einen neuen Weg weist zur Erweiterung unserer im wesentlichen auf optischen Beobachtungen fußenden Kenntnis dieser eigenartigen Stromquellen. Die neuen Befunde lassen außerdem erkennen, wieweit es in praktischer Hinsicht möglich ist, diese Zellen etwa zu Kathodenstrahlmessungen zu verwenden.

Notizen: Zusammenfassung Die Arbeit enthält mehrere systematisch durchgeführte Beobachtungsreihen über das Verhalten des Selenphotoelements bei Erregung durch Licht, die neue Gesichtspunkte für die theoretische Beurteilung der bisher nicht voll erkannten Eigenschaften dieses Elements liefern. Es handelt sich insbesondere um das Verhalten im stationären elektrischen Feld, um die Bedeutung der erregenden Lichtart und Lichtstromdichte und um den Einfluß der Temperatur.