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Electroinitiated oligomerization of methyl acrylate in methanol solution (1975)

Albeck, Michael ; Karoly, Aharon

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 13 (1975), S. 2699-2707

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The electroinitiated oligomerization of methyl acrylate in methanol solution in the presence of lithium acetate was studied. It was found that in this system the initiator is the methyl radical (obtained from anodic oxidation of acetate ion), and the major termination step is the abstraction of hydrogen radical from methanol by the growing oligomer chain. Eleven compounds were found to be formed in the reaction. A reaction sequence for their formation together with an electric balance for the reactions is given.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1975.170131205

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