ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of S + OH → SO + H (1) and SO + OH → SO2 + H (2) were studied in a discharge flow reactor coupled to an EPR spectrometer. The rate constants obtained under the pseudo-first-order conditions with an excess of S or SO were found to be k1 = (6.6 ± 1.4) × 10-11 and k2 = (8.4 ± 1.5) × 10-11 at room temperature. Units are cm3/molec·sec. Besides no reactivity was observed between S and CO2 at 298 K and between CIO and SO2 up to 711 K.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550110603
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