ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract Orthorhombic crystals of the title compound, C7H16ClNO2SSn, belong to space groupP212121, witha = 6.658(5),b = 10.974(3),c = 17.144(5) Å, andZ = 4. The diffractometer data, measured with CuKα radiation, has been refined to anR index of 0.053 for 1110 observed terms. The geometry about the Sn atom in the monomeric complex units is distorted trigonal bipyramidal; the N and Cl atoms are in the apical positions, and the Sn lies at 0.107(1) Å from the equatorial plane. The Sn-Cl, Sn-S, and Sn-N bonds have lengths 2.523(4), 2.413(3), and 2.434(12) respectively, and the angle N-Sn is 166.9(3) °.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01387558
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