ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A series of monomethyl, monoacyl glycols was protonated in a flowing afterglow system. In the subsequent fragmentation reactions acetic acid was found to be a better leaving group than methanol, but the acetoxy group was shown to participate in methanol expulsion under certain conditions. The effects of leaving group ability, anchimeric assistance, stereochemistry and steric hindrance on the fragmentation patterns of the protonated molecular ions are discussed.
Additional Material:
7 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210131210
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